Articles | Volume 15, issue 3
https://doi.org/10.5194/esd-15-801-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/esd-15-801-2024
© Author(s) 2024. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
Research article
| 
21 Jun 2024
Research article |
| 21 Jun 2024
| 21 Jun 2024
Natural marine bromoform emissions in the fully coupled ocean–atmosphere model NorESM2
GEOMAR Helmholtz Centre for Ocean Research Kiel, 24148 Kiel, Germany
Section for Meteorology and Oceanography, Department of Geosciences, University of Oslo, 0371 Oslo, Norway
Jerry F. Tjiputra
NORCE Norwegian Research Centre and Bjerknes Centre for Climate Research, 5007 Bergen, Norway
Dirk J. L. Olivié
Norwegian Meteorological Institute, 0313 Oslo, Norway
Birgit Quack
GEOMAR Helmholtz Centre for Ocean Research Kiel, 24148 Kiel, Germany
Section for Meteorology and Oceanography, Department of Geosciences, University of Oslo, 0371 Oslo, Norway
Related authors
Li Zhou, Dennis Booge, Miming Zhang, and Christa A. Marandino
Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, https://doi.org/10.5194/bg-19-5021-2022, 2022
Short summary
Short summary
Trace gas air–sea exchange exerts an important control on air quality and climate, especially in the Southern Ocean (SO). Almost all of the measurements there are skewed to summer, but it is essential to expand our measurement database over greater temporal and spatial scales. Therefore, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the SO. The observations of isoprene are the first in the winter in the SO.
Sonja Gindorf, Hermann W. Bange, Dennis Booge, and Annette Kock
Biogeosciences, 19, 4993–5006, https://doi.org/10.5194/bg-19-4993-2022, https://doi.org/10.5194/bg-19-4993-2022, 2022
Short summary
Short summary
Methane is a climate-relevant greenhouse gas which is emitted to the atmosphere from coastal areas such as the Baltic Sea. We measured the methane concentration in the water column of the western Kiel Bight. Methane concentrations were higher in September than in June. We found no relationship between the 2018 European heatwave and methane concentrations. Our results show that the methane distribution in the water column is strongly affected by temporal and spatial variabilities.
Yanan Zhao, Dennis Booge, Christa A. Marandino, Cathleen Schlundt, Astrid Bracher, Elliot L. Atlas, Jonathan Williams, and Hermann W. Bange
Biogeosciences, 19, 701–714, https://doi.org/10.5194/bg-19-701-2022, https://doi.org/10.5194/bg-19-701-2022, 2022
Short summary
Short summary
We present here, for the first time, simultaneously measured dimethylsulfide (DMS) seawater concentrations and DMS atmospheric mole fractions from the Peruvian upwelling region during two cruises in December 2012 and October 2015. Our results indicate low oceanic DMS concentrations and atmospheric DMS molar fractions in surface waters and the atmosphere, respectively. In addition, the Peruvian upwelling region was identified as an insignificant source of DMS emissions during both periods.
Yanan Zhao, Cathleen Schlundt, Dennis Booge, and Hermann W. Bange
Biogeosciences, 18, 2161–2179, https://doi.org/10.5194/bg-18-2161-2021, https://doi.org/10.5194/bg-18-2161-2021, 2021
Short summary
Short summary
We present a unique and comprehensive time-series study of biogenic sulfur compounds in the southwestern Baltic Sea, from 2009 to 2018. Dimethyl sulfide is one of the key players regulating global climate change, as well as dimethylsulfoniopropionate and dimethyl sulfoxide. Their decadal trends did not follow increasing temperature but followed some algae group abundances at the Boknis Eck Time Series Station.
William J. Collins, Fiona M. O'Connor, Rachael E. Byrom, Øivind Hodnebrog, Patrick Jöckel, Mariano Mertens, Gunnar Myhre, Matthias Nützel, Dirk Olivié, Ragnhild Bieltvedt Skeie, Laura Stecher, Larry W. Horowitz, Vaishali Naik, Gregory Faluvegi, Ulas Im, Lee T. Murray, Drew Shindell, Kostas Tsigaridis, Nathan Luke Abraham, and James Keeble
Atmos. Chem. Phys., 25, 9031–9060, https://doi.org/10.5194/acp-25-9031-2025, https://doi.org/10.5194/acp-25-9031-2025, 2025
Short summary
Short summary
We used 7 climate models that include atmospheric chemistry and find that in a scenario with weak controls on air quality, the warming effects (over 2015 to 2050) of decreases in ozone-depleting substances and increases in air quality pollutants are approximately equal and would make ozone the second highest contributor to warming over this period. We find that for stratospheric ozone recovery, the standard measure of climate effects underestimates a more comprehensive measure.
Victor Brovkin, Benjamin M. Sanderson, Noel G. Brizuela, Tomohiro Hajima, Tatiana Ilyina, Chris D. Jones, Charles Koven, David Lawrence, Peter Lawrence, Hongmei Li, Spencer Liddcoat, Anastasia Romanou, Roland Séférian, Lori T. Sentman, Abigail L. S. Swann, Jerry Tjiputra, Tilo Ziehn, and Alexander J. Winkler
EGUsphere, https://doi.org/10.5194/egusphere-2025-3270, https://doi.org/10.5194/egusphere-2025-3270, 2025
Short summary
Short summary
Idealized experiments with Earth system models provide a basis for understanding the response of the carbon cycle to emissions. We show that most models exhibit a quasi-linear relationship between cumulative carbon uptake on land and in the ocean and hypothesize that this relationship does not depend on emission pathways. We reduce the coupled system to only one differential equation, which represents a powerful simplification of the Earth system dynamics as a function of fossil fuel emissions.
Forrest M. Hoffman, Birgit Hassler, Ranjini Swaminathan, Jared Lewis, Bouwe Andela, Nathaniel Collier, Dóra Hegedűs, Jiwoo Lee, Charlotte Pascoe, Mika Pflüger, Martina Stockhause, Paul Ullrich, Min Xu, Lisa Bock, Felicity Chun, Bettina K. Gier, Douglas I. Kelley, Axel Lauer, Julien Lenhardt, Manuel Schlund, Mohanan G. Sreeush, Katja Weigel, Ed Blockley, Rebecca Beadling, Romain Beucher, Demiso D. Dugassa, Valerio Lembo, Jianhua Lu, Swen Brands, Jerry Tjiputra, Elizaveta Malinina, Brian Mederios, Enrico Scoccimarro, Jeremy Walton, Philip Kershaw, André L. Marquez, Malcolm J. Roberts, Eleanor O’Rourke, Elisabeth Dingley, Briony Turner, Helene Hewitt, and John P. Dunne
EGUsphere, https://doi.org/10.5194/egusphere-2025-2685, https://doi.org/10.5194/egusphere-2025-2685, 2025
This preprint is open for discussion and under review for Geoscientific Model Development (GMD).
Short summary
Short summary
As Earth system models become more complex, rapid and comprehensive evaluation through comparison with observational data is necessary. The upcoming Assessment Fast Track for the Seventh Phase of the Coupled Model Intercomparison Project (CMIP7) will require fast analysis. This paper describes a new Rapid Evaluation Framework (REF) that was developed for the Assessment Fast Track that will be run at the Earth System Grid Federation (ESGF) to inform the community about the performance of models.
Damien Couespel, Xabier Davila, Nadine Goris, Emil Jeansson, Siv K. Lauvset, and Jerry Tjiputra
EGUsphere, https://doi.org/10.5194/egusphere-2025-2566, https://doi.org/10.5194/egusphere-2025-2566, 2025
This preprint is open for discussion and under review for Biogeosciences (BG).
Short summary
Short summary
Remineralised carbon storage is projected to increase along the 21st century, but the magnitude of increase varies depending on the Earth system models. To constrain the projections, we explore the relation between remineralised carbon and circulation in the deep ocean. Comparing model simulations and observations, we show that models overestimate the sensitivity of remineralised carbon storage to circulation slowdown, suggesting an overestimation of the future remineralised carbon increase.
Ove W. Haugvaldstad, Dirk Olivié, Trude Storelvmo, and Michael Schulz
EGUsphere, https://doi.org/10.5194/egusphere-2025-1030, https://doi.org/10.5194/egusphere-2025-1030, 2025
Short summary
Short summary
Our study examine what would happen if desert dust in the atmosphere doubled, motivated by dust sedimentation records showing a large increase in dust levels since industrialization began. Using climate model simulations, we assess how more dust affects Earth's energy balance and rainfall. We found that models disagree on whether more dust overall cools or warms the planet. Additionally, more dust tends to reduce rainfall because it absorbs radiation and encourages the formation of ice clouds.
Tómas Zoëga, Trude Storelvmo, and Kirstin Krüger
Atmos. Chem. Phys., 25, 2989–3010, https://doi.org/10.5194/acp-25-2989-2025, https://doi.org/10.5194/acp-25-2989-2025, 2025
Short summary
Short summary
We use an Earth system model to systematically investigate the climate response to high-latitude effusive volcanic eruptions as a function of eruption season and size, with a focus on the Arctic. We find that different seasons strongly modulate the climate response, with Arctic surface warming observed in winter and cooling in summer. Additionally, as eruptions increase in terms of sulfur dioxide emissions, the climate response becomes increasingly insensitive to variations in emission strength.
Philip John Wallhead, Jörg Schwinger, Jerry Tjiputra, Trond Kristiansen, and Richard Garth James Bellerby
Earth Syst. Sci. Data Discuss., https://doi.org/10.5194/essd-2025-76, https://doi.org/10.5194/essd-2025-76, 2025
Preprint under review for ESSD
Short summary
Short summary
We developed a novel method to combine ocean data from observations and models, and applied it to produce gridded estimates of nutrients, oxygen, dissolved inorganic carbon and total alkalinity concentrations at latitudes >40° N and years 1980–2020. The new estimates showed improved accuracy and coverage relative to previous estimates, but highlighted remaining uncertainty in some poorly sampled regions. The work was largely motivated by a need for accurate input data for regional ocean models.
Lise Seland Graff, Jerry Tjiputra, Ada Gjermundsen, Andreas Born, Jens Boldingh Debernard, Heiko Goelzer, Yan-Chun He, Petra Margaretha Langebroek, Aleksi Nummelin, Dirk Olivié, Øyvind Seland, Trude Storelvmo, Mats Bentsen, Chuncheng Guo, Andrea Rosendahl, Dandan Tao, Thomas Toniazzo, Camille Li, Stephen Outten, and Michael Schulz
EGUsphere, https://doi.org/10.5194/egusphere-2025-472, https://doi.org/10.5194/egusphere-2025-472, 2025
Short summary
Short summary
The magnitude of future Arctic amplification is highly uncertain. Using the Norwegian Earth system model, we explore the effect of improving the representation of clouds, ocean eddies, the Greenland ice sheet, sea ice, and ozone on the projected Arctic winter warming in a coordinated experiment set. These improvements all lead to enhanced projected Arctic warming, with the largest changes found in the sea-ice retreat regions and the largest uncertainty on the Atlantic side.
Yona Silvy, Thomas L. Frölicher, Jens Terhaar, Fortunat Joos, Friedrich A. Burger, Fabrice Lacroix, Myles Allen, Raffaele Bernardello, Laurent Bopp, Victor Brovkin, Jonathan R. Buzan, Patricia Cadule, Martin Dix, John Dunne, Pierre Friedlingstein, Goran Georgievski, Tomohiro Hajima, Stuart Jenkins, Michio Kawamiya, Nancy Y. Kiang, Vladimir Lapin, Donghyun Lee, Paul Lerner, Nadine Mengis, Estela A. Monteiro, David Paynter, Glen P. Peters, Anastasia Romanou, Jörg Schwinger, Sarah Sparrow, Eric Stofferahn, Jerry Tjiputra, Etienne Tourigny, and Tilo Ziehn
Earth Syst. Dynam., 15, 1591–1628, https://doi.org/10.5194/esd-15-1591-2024, https://doi.org/10.5194/esd-15-1591-2024, 2024
Short summary
Short summary
The adaptive emission reduction approach is applied with Earth system models to generate temperature stabilization simulations. These simulations provide compatible emission pathways and budgets for a given warming level, uncovering uncertainty ranges previously missing in the Coupled Model Intercomparison Project scenarios. These target-based emission-driven simulations offer a more coherent assessment across models for studying both the carbon cycle and its impacts under climate stabilization.
Benjamin Mark Sanderson, Victor Brovkin, Rosie Fisher, David Hohn, Tatiana Ilyina, Chris Jones, Torben Koenigk, Charles Koven, Hongmei Li, David Lawrence, Peter Lawrence, Spencer Liddicoat, Andrew Macdougall, Nadine Mengis, Zebedee Nicholls, Eleanor O'Rourke, Anastasia Romanou, Marit Sandstad, Jörg Schwinger, Roland Seferian, Lori Sentman, Isla Simpson, Chris Smith, Norman Steinert, Abigail Swann, Jerry Tjiputra, and Tilo Ziehn
EGUsphere, https://doi.org/10.5194/egusphere-2024-3356, https://doi.org/10.5194/egusphere-2024-3356, 2024
Short summary
Short summary
This study investigates how climate models warm in response to simplified carbon emissions trajectories, refining understanding of climate reversibility and commitment. Metrics are defined for warming response to cumulative emissions and for the cessation or ramp-down to net-zero and net-negative levels. Results indicate that previous concentration-driven experiments may have overstated zero emissions commitment due to emissions rates exceeding historical levels.
Shunya Koseki, Lander R. Crespo, Jerry Tjiputra, Filippa Fransner, Noel S. Keenlyside, and David Rivas
Biogeosciences, 21, 4149–4168, https://doi.org/10.5194/bg-21-4149-2024, https://doi.org/10.5194/bg-21-4149-2024, 2024
Short summary
Short summary
We investigated how the physical biases of an Earth system model influence the marine biogeochemical processes in the tropical Atlantic. With four different configurations of the model, we have shown that the versions with better SST reproduction tend to better represent the primary production and air–sea CO2 flux in terms of climatology, seasonal cycle, and response to climate variability.
Alkiviadis Kalisoras, Aristeidis K. Georgoulias, Dimitris Akritidis, Robert J. Allen, Vaishali Naik, Chaincy Kuo, Sophie Szopa, Pierre Nabat, Dirk Olivié, Twan van Noije, Philippe Le Sager, David Neubauer, Naga Oshima, Jane Mulcahy, Larry W. Horowitz, and Prodromos Zanis
Atmos. Chem. Phys., 24, 7837–7872, https://doi.org/10.5194/acp-24-7837-2024, https://doi.org/10.5194/acp-24-7837-2024, 2024
Short summary
Short summary
Effective radiative forcing (ERF) is a metric for estimating how human activities and natural agents change the energy flow into and out of the Earth’s climate system. We investigate the anthropogenic aerosol ERF, and we estimate the contribution of individual processes to the total ERF using simulations from Earth system models within the Coupled Model Intercomparison Project Phase 6 (CMIP6). Our findings highlight that aerosol–cloud interactions drive ERF variability during the last 150 years.
Zhihong Zhuo, Herman F. Fuglestvedt, Matthew Toohey, and Kirstin Krüger
Atmos. Chem. Phys., 24, 6233–6249, https://doi.org/10.5194/acp-24-6233-2024, https://doi.org/10.5194/acp-24-6233-2024, 2024
Short summary
Short summary
This work simulated volcanic eruptions with varied eruption source parameters under different initial conditions with a fully coupled Earth system model. We show that initial atmospheric conditions control the meridional distribution of volcanic volatiles and modulate volcanic forcing and subsequent climate and environmental impacts of tropical and Northern Hemisphere extratropical eruptions. This highlights the potential for predicting these impacts as early as the first post-eruption month.
Ali Asaadi, Jörg Schwinger, Hanna Lee, Jerry Tjiputra, Vivek Arora, Roland Séférian, Spencer Liddicoat, Tomohiro Hajima, Yeray Santana-Falcón, and Chris D. Jones
Biogeosciences, 21, 411–435, https://doi.org/10.5194/bg-21-411-2024, https://doi.org/10.5194/bg-21-411-2024, 2024
Short summary
Short summary
Carbon cycle feedback metrics are employed to assess phases of positive and negative CO2 emissions. When emissions become negative, we find that the model disagreement in feedback metrics increases more strongly than expected from the assumption that the uncertainties accumulate linearly with time. The geographical patterns of such metrics over land highlight that differences in response between tropical/subtropical and temperate/boreal ecosystems are a major source of model disagreement.
Hamza Ahsan, Hailong Wang, Jingbo Wu, Mingxuan Wu, Steven J. Smith, Susanne Bauer, Harrison Suchyta, Dirk Olivié, Gunnar Myhre, Hitoshi Matsui, Huisheng Bian, Jean-François Lamarque, Ken Carslaw, Larry Horowitz, Leighton Regayre, Mian Chin, Michael Schulz, Ragnhild Bieltvedt Skeie, Toshihiko Takemura, and Vaishali Naik
Atmos. Chem. Phys., 23, 14779–14799, https://doi.org/10.5194/acp-23-14779-2023, https://doi.org/10.5194/acp-23-14779-2023, 2023
Short summary
Short summary
We examine the impact of the assumed effective height of SO2 injection, SO2 and BC emission seasonality, and the assumed fraction of SO2 emissions injected as SO4 on climate and chemistry model results. We find that the SO2 injection height has a large impact on surface SO2 concentrations and, in some models, radiative flux. These assumptions are a
hiddensource of inter-model variability and may be leading to bias in some climate model results.
Veli Çağlar Yumruktepe, Erik Askov Mousing, Jerry Tjiputra, and Annette Samuelsen
Geosci. Model Dev., 16, 6875–6897, https://doi.org/10.5194/gmd-16-6875-2023, https://doi.org/10.5194/gmd-16-6875-2023, 2023
Short summary
Short summary
We present an along BGC-Argo track 1D modelling framework. The model physics is constrained by the BGC-Argo temperature and salinity profiles to reduce the uncertainties related to mixed layer dynamics, allowing the evaluation of the biogeochemical formulation and parameterization. We objectively analyse the model with BGC-Argo and satellite data and improve the model biogeochemical dynamics. We present the framework, example cases and routines for model improvement and implementations.
Christoph Heinze, Thorsten Blenckner, Peter Brown, Friederike Fröb, Anne Morée, Adrian L. New, Cara Nissen, Stefanie Rynders, Isabel Seguro, Yevgeny Aksenov, Yuri Artioli, Timothée Bourgeois, Friedrich Burger, Jonathan Buzan, B. B. Cael, Veli Çağlar Yumruktepe, Melissa Chierici, Christopher Danek, Ulf Dieckmann, Agneta Fransson, Thomas Frölicher, Giovanni Galli, Marion Gehlen, Aridane G. González, Melchor Gonzalez-Davila, Nicolas Gruber, Örjan Gustafsson, Judith Hauck, Mikko Heino, Stephanie Henson, Jenny Hieronymus, I. Emma Huertas, Fatma Jebri, Aurich Jeltsch-Thömmes, Fortunat Joos, Jaideep Joshi, Stephen Kelly, Nandini Menon, Precious Mongwe, Laurent Oziel, Sólveig Ólafsdottir, Julien Palmieri, Fiz F. Pérez, Rajamohanan Pillai Ranith, Juliano Ramanantsoa, Tilla Roy, Dagmara Rusiecka, J. Magdalena Santana Casiano, Yeray Santana-Falcón, Jörg Schwinger, Roland Séférian, Miriam Seifert, Anna Shchiptsova, Bablu Sinha, Christopher Somes, Reiner Steinfeldt, Dandan Tao, Jerry Tjiputra, Adam Ulfsbo, Christoph Völker, Tsuyoshi Wakamatsu, and Ying Ye
Biogeosciences Discuss., https://doi.org/10.5194/bg-2023-182, https://doi.org/10.5194/bg-2023-182, 2023
Revised manuscript not accepted
Short summary
Short summary
For assessing the consequences of human-induced climate change for the marine realm, it is necessary to not only look at gradual changes but also at abrupt changes of environmental conditions. We summarise abrupt changes in ocean warming, acidification, and oxygen concentration as the key environmental factors for ecosystems. Taking these abrupt changes into account requires greenhouse gas emissions to be reduced to a larger extent than previously thought to limit respective damage.
Claire Waelbroeck, Jerry Tjiputra, Chuncheng Guo, Kerim H. Nisancioglu, Eystein Jansen, Natalia Vázquez Riveiros, Samuel Toucanne, Frédérique Eynaud, Linda Rossignol, Fabien Dewilde, Elodie Marchès, Susana Lebreiro, and Silvia Nave
Clim. Past, 19, 901–913, https://doi.org/10.5194/cp-19-901-2023, https://doi.org/10.5194/cp-19-901-2023, 2023
Short summary
Short summary
The precise geometry and extent of Atlantic circulation changes that accompanied rapid climate changes of the last glacial period are still unknown. Here, we combine carbon isotopic records from 18 Atlantic sediment cores with numerical simulations and decompose the carbon isotopic change across a cold-to-warm transition into remineralization and circulation components. Our results show that the replacement of southern-sourced by northern-sourced water plays a dominant role below ~ 3000 m depth.
Nadine Goris, Klaus Johannsen, and Jerry Tjiputra
Geosci. Model Dev., 16, 2095–2117, https://doi.org/10.5194/gmd-16-2095-2023, https://doi.org/10.5194/gmd-16-2095-2023, 2023
Short summary
Short summary
Climate projections of a high-CO2 future are highly uncertain. A new study provides a novel approach to identifying key regions that dynamically explain the model uncertainty. To yield an accurate estimate of the future North Atlantic carbon uptake, we find that a correct simulation of the upper- and interior-ocean volume transport at 25–30° N is key. However, results indicate that models rarely perform well for both indicators and point towards inconsistencies within the model ensemble.
Alban Planchat, Lester Kwiatkowski, Laurent Bopp, Olivier Torres, James R. Christian, Momme Butenschön, Tomas Lovato, Roland Séférian, Matthew A. Chamberlain, Olivier Aumont, Michio Watanabe, Akitomo Yamamoto, Andrew Yool, Tatiana Ilyina, Hiroyuki Tsujino, Kristen M. Krumhardt, Jörg Schwinger, Jerry Tjiputra, John P. Dunne, and Charles Stock
Biogeosciences, 20, 1195–1257, https://doi.org/10.5194/bg-20-1195-2023, https://doi.org/10.5194/bg-20-1195-2023, 2023
Short summary
Short summary
Ocean alkalinity is critical to the uptake of atmospheric carbon and acidification in surface waters. We review the representation of alkalinity and the associated calcium carbonate cycle in Earth system models. While many parameterizations remain present in the latest generation of models, there is a general improvement in the simulated alkalinity distribution. This improvement is related to an increase in the export of biotic calcium carbonate, which closer resembles observations.
Evelien van Dijk, Ingar Mørkestøl Gundersen, Anna de Bode, Helge Høeg, Kjetil Loftsgarden, Frode Iversen, Claudia Timmreck, Johann Jungclaus, and Kirstin Krüger
Clim. Past, 19, 357–398, https://doi.org/10.5194/cp-19-357-2023, https://doi.org/10.5194/cp-19-357-2023, 2023
Short summary
Short summary
The mid-6th century was one of the coldest periods of the last 2000 years as characterized by great societal changes. Here, we study the effect of the volcanic double event in 536 CE and 540 CE on climate and society in southern Norway. The combined climate and growing degree day models and high-resolution pollen and archaeological records reveal that the northern and western sites are vulnerable to crop failure with possible abandonment of farms, whereas the southeastern site is more resilient.
Shuang Gao, Jörg Schwinger, Jerry Tjiputra, Ingo Bethke, Jens Hartmann, Emilio Mayorga, and Christoph Heinze
Biogeosciences, 20, 93–119, https://doi.org/10.5194/bg-20-93-2023, https://doi.org/10.5194/bg-20-93-2023, 2023
Short summary
Short summary
We assess the impact of riverine nutrients and carbon (C) on projected marine primary production (PP) and C uptake using a fully coupled Earth system model. Riverine inputs alleviate nutrient limitation and thus lessen the projected PP decline by up to 0.7 Pg C yr−1 globally. The effect of increased riverine C may be larger than the effect of nutrient inputs in the future on the projected ocean C uptake, while in the historical period increased nutrient inputs are considered the largest driver.
Shih-Wei Fang, Claudia Timmreck, Johann Jungclaus, Kirstin Krüger, and Hauke Schmidt
Earth Syst. Dynam., 13, 1535–1555, https://doi.org/10.5194/esd-13-1535-2022, https://doi.org/10.5194/esd-13-1535-2022, 2022
Short summary
Short summary
The early 19th century was the coldest period over the past 500 years, when strong tropical volcanic events and a solar minimum coincided. This study quantifies potential surface cooling from the solar and volcanic forcing in the early 19th century with large ensemble simulations, and identifies the regions that their impacts cannot be simply additive. The cooling perspective of Arctic amplification exists in both solar and post-volcano period with the albedo feedback as the main contribution.
Li Zhou, Dennis Booge, Miming Zhang, and Christa A. Marandino
Biogeosciences, 19, 5021–5040, https://doi.org/10.5194/bg-19-5021-2022, https://doi.org/10.5194/bg-19-5021-2022, 2022
Short summary
Short summary
Trace gas air–sea exchange exerts an important control on air quality and climate, especially in the Southern Ocean (SO). Almost all of the measurements there are skewed to summer, but it is essential to expand our measurement database over greater temporal and spatial scales. Therefore, we report measured concentrations of dimethylsulfide (DMS, as well as related sulfur compounds) and isoprene in the Atlantic sector of the SO. The observations of isoprene are the first in the winter in the SO.
Sonja Gindorf, Hermann W. Bange, Dennis Booge, and Annette Kock
Biogeosciences, 19, 4993–5006, https://doi.org/10.5194/bg-19-4993-2022, https://doi.org/10.5194/bg-19-4993-2022, 2022
Short summary
Short summary
Methane is a climate-relevant greenhouse gas which is emitted to the atmosphere from coastal areas such as the Baltic Sea. We measured the methane concentration in the water column of the western Kiel Bight. Methane concentrations were higher in September than in June. We found no relationship between the 2018 European heatwave and methane concentrations. Our results show that the methane distribution in the water column is strongly affected by temporal and spatial variabilities.
Ville Leinonen, Harri Kokkola, Taina Yli-Juuti, Tero Mielonen, Thomas Kühn, Tuomo Nieminen, Simo Heikkinen, Tuuli Miinalainen, Tommi Bergman, Ken Carslaw, Stefano Decesari, Markus Fiebig, Tareq Hussein, Niku Kivekäs, Radovan Krejci, Markku Kulmala, Ari Leskinen, Andreas Massling, Nikos Mihalopoulos, Jane P. Mulcahy, Steffen M. Noe, Twan van Noije, Fiona M. O'Connor, Colin O'Dowd, Dirk Olivie, Jakob B. Pernov, Tuukka Petäjä, Øyvind Seland, Michael Schulz, Catherine E. Scott, Henrik Skov, Erik Swietlicki, Thomas Tuch, Alfred Wiedensohler, Annele Virtanen, and Santtu Mikkonen
Atmos. Chem. Phys., 22, 12873–12905, https://doi.org/10.5194/acp-22-12873-2022, https://doi.org/10.5194/acp-22-12873-2022, 2022
Short summary
Short summary
We provide the first extensive comparison of detailed aerosol size distribution trends between in situ observations from Europe and five different earth system models. We investigated aerosol modes (nucleation, Aitken, and accumulation) separately and were able to show the differences between measured and modeled trends and especially their seasonal patterns. The differences in model results are likely due to complex effects of several processes instead of certain specific model features.
Pradeebane Vaittinada Ayar, Laurent Bopp, Jim R. Christian, Tatiana Ilyina, John P. Krasting, Roland Séférian, Hiroyuki Tsujino, Michio Watanabe, Andrew Yool, and Jerry Tjiputra
Earth Syst. Dynam., 13, 1097–1118, https://doi.org/10.5194/esd-13-1097-2022, https://doi.org/10.5194/esd-13-1097-2022, 2022
Short summary
Short summary
The El Niño–Southern Oscillation is the main driver for the natural variability of global atmospheric CO2. It modulates the CO2 fluxes in the tropical Pacific with anomalous CO2 influx during El Niño and outflux during La Niña. This relationship is projected to reverse by half of Earth system models studied here under the business-as-usual scenario. This study shows models that simulate a positive bias in surface carbonate concentrations simulate a shift in the ENSO–CO2 flux relationship.
Evelien van Dijk, Johann Jungclaus, Stephan Lorenz, Claudia Timmreck, and Kirstin Krüger
Clim. Past, 18, 1601–1623, https://doi.org/10.5194/cp-18-1601-2022, https://doi.org/10.5194/cp-18-1601-2022, 2022
Short summary
Short summary
A double volcanic eruption in 536 and 540 CE caused one of the coldest decades during the last 2000 years. We analyzed new climate model simulations from that period and found a cooling of up to 2°C and a sea-ice extent up to 200 km further south. Complex interactions between sea ice and ocean circulation lead to a reduction in the northward ocean heat transport, which makes the sea ice extend further south; this in turn leads to a surface cooling up to 20 years after the eruptions.
Yue Jia, Birgit Quack, Robert D. Kinley, Ignacio Pisso, and Susann Tegtmeier
Atmos. Chem. Phys., 22, 7631–7646, https://doi.org/10.5194/acp-22-7631-2022, https://doi.org/10.5194/acp-22-7631-2022, 2022
Short summary
Short summary
In this study, we assessed the potential risks of bromoform released from Asparagopsis farming near Australia for the stratospheric ozone layer by analyzing different cultivation scenarios. We conclude that the intended operation of Asparagopsis seaweed cultivation farms with an annual yield to meet the needs of 50 % of feedlots and cattle in either open-ocean or terrestrial cultures in Australia will not impact the ozone layer under normal operating conditions.
Susann Tegtmeier, Christa Marandino, Yue Jia, Birgit Quack, and Anoop S. Mahajan
Atmos. Chem. Phys., 22, 6625–6676, https://doi.org/10.5194/acp-22-6625-2022, https://doi.org/10.5194/acp-22-6625-2022, 2022
Short summary
Short summary
In the atmosphere over the Indian Ocean, intense anthropogenic pollution from Southeast Asia mixes with pristine oceanic air. During the winter monsoon, high pollution levels are regularly observed over the entire northern Indian Ocean, while during the summer monsoon, clean air dominates. Here, we review current progress in detecting and understanding atmospheric gas-phase composition over the Indian Ocean and its impacts on the upper atmosphere, oceanic biogeochemistry, and marine ecosystems.
Cynthia H. Whaley, Rashed Mahmood, Knut von Salzen, Barbara Winter, Sabine Eckhardt, Stephen Arnold, Stephen Beagley, Silvia Becagli, Rong-You Chien, Jesper Christensen, Sujay Manish Damani, Xinyi Dong, Konstantinos Eleftheriadis, Nikolaos Evangeliou, Gregory Faluvegi, Mark Flanner, Joshua S. Fu, Michael Gauss, Fabio Giardi, Wanmin Gong, Jens Liengaard Hjorth, Lin Huang, Ulas Im, Yugo Kanaya, Srinath Krishnan, Zbigniew Klimont, Thomas Kühn, Joakim Langner, Kathy S. Law, Louis Marelle, Andreas Massling, Dirk Olivié, Tatsuo Onishi, Naga Oshima, Yiran Peng, David A. Plummer, Olga Popovicheva, Luca Pozzoli, Jean-Christophe Raut, Maria Sand, Laura N. Saunders, Julia Schmale, Sangeeta Sharma, Ragnhild Bieltvedt Skeie, Henrik Skov, Fumikazu Taketani, Manu A. Thomas, Rita Traversi, Kostas Tsigaridis, Svetlana Tsyro, Steven Turnock, Vito Vitale, Kaley A. Walker, Minqi Wang, Duncan Watson-Parris, and Tahya Weiss-Gibbons
Atmos. Chem. Phys., 22, 5775–5828, https://doi.org/10.5194/acp-22-5775-2022, https://doi.org/10.5194/acp-22-5775-2022, 2022
Short summary
Short summary
Air pollutants, like ozone and soot, play a role in both global warming and air quality. Atmospheric models are often used to provide information to policy makers about current and future conditions under different emissions scenarios. In order to have confidence in those simulations, in this study we compare simulated air pollution from 18 state-of-the-art atmospheric models to measured air pollution in order to assess how well the models perform.
Guangyu Liu, Toshihiko Hirooka, Nawo Eguchi, and Kirstin Krüger
Atmos. Chem. Phys., 22, 3493–3505, https://doi.org/10.5194/acp-22-3493-2022, https://doi.org/10.5194/acp-22-3493-2022, 2022
Short summary
Short summary
The sudden stratospheric warming (SSW) event that occurred in September 2019 in the Southern Hemisphere was analyzed. A large warming and decelerated westerly winds were observed in the southern polar region. Since a reversal from westerly to easterly winds did not take place SSW2019 was classified as a minor SSW. The total wave forcing and the contribution from PW1 were larger in 2019. The strong and long-lasting planetary-scale waves with zonal wavenumber 1 played a role in SSW2019.
Filippa Fransner, Friederike Fröb, Jerry Tjiputra, Nadine Goris, Siv K. Lauvset, Ingunn Skjelvan, Emil Jeansson, Abdirahman Omar, Melissa Chierici, Elizabeth Jones, Agneta Fransson, Sólveig R. Ólafsdóttir, Truls Johannessen, and Are Olsen
Biogeosciences, 19, 979–1012, https://doi.org/10.5194/bg-19-979-2022, https://doi.org/10.5194/bg-19-979-2022, 2022
Short summary
Short summary
Ocean acidification, a direct consequence of the CO2 release by human activities, is a serious threat to marine ecosystems. In this study, we conduct a detailed investigation of the acidification of the Nordic Seas, from 1850 to 2100, by using a large set of samples taken during research cruises together with numerical model simulations. We estimate the effects of changes in different environmental factors on the rate of acidification and its potential effects on cold-water corals.
Yanan Zhao, Dennis Booge, Christa A. Marandino, Cathleen Schlundt, Astrid Bracher, Elliot L. Atlas, Jonathan Williams, and Hermann W. Bange
Biogeosciences, 19, 701–714, https://doi.org/10.5194/bg-19-701-2022, https://doi.org/10.5194/bg-19-701-2022, 2022
Short summary
Short summary
We present here, for the first time, simultaneously measured dimethylsulfide (DMS) seawater concentrations and DMS atmospheric mole fractions from the Peruvian upwelling region during two cruises in December 2012 and October 2015. Our results indicate low oceanic DMS concentrations and atmospheric DMS molar fractions in surface waters and the atmosphere, respectively. In addition, the Peruvian upwelling region was identified as an insignificant source of DMS emissions during both periods.
Paul D. Hamer, Virginie Marécal, Ryan Hossaini, Michel Pirre, Gisèle Krysztofiak, Franziska Ziska, Andreas Engel, Stephan Sala, Timo Keber, Harald Bönisch, Elliot Atlas, Kirstin Krüger, Martyn Chipperfield, Valery Catoire, Azizan A. Samah, Marcel Dorf, Phang Siew Moi, Hans Schlager, and Klaus Pfeilsticker
Atmos. Chem. Phys., 21, 16955–16984, https://doi.org/10.5194/acp-21-16955-2021, https://doi.org/10.5194/acp-21-16955-2021, 2021
Short summary
Short summary
Bromoform is a stratospheric ozone-depleting gas released by seaweed and plankton transported to the stratosphere via convection in the tropics. We study the chemical interactions of bromoform and its derivatives within convective clouds using a cloud-scale model and observations. Our findings are that soluble bromine gases are efficiently washed out and removed within the convective clouds and that most bromine is transported vertically to the upper troposphere in the form of bromoform.
Ingo Bethke, Yiguo Wang, François Counillon, Noel Keenlyside, Madlen Kimmritz, Filippa Fransner, Annette Samuelsen, Helene Langehaug, Lea Svendsen, Ping-Gin Chiu, Leilane Passos, Mats Bentsen, Chuncheng Guo, Alok Gupta, Jerry Tjiputra, Alf Kirkevåg, Dirk Olivié, Øyvind Seland, Julie Solsvik Vågane, Yuanchao Fan, and Tor Eldevik
Geosci. Model Dev., 14, 7073–7116, https://doi.org/10.5194/gmd-14-7073-2021, https://doi.org/10.5194/gmd-14-7073-2021, 2021
Short summary
Short summary
The Norwegian Climate Prediction Model version 1 (NorCPM1) is a new research tool for performing climate reanalyses and seasonal-to-decadal climate predictions. It adds data assimilation capability to the Norwegian Earth System Model version 1 (NorESM1) and has contributed output to the Decadal Climate Prediction Project (DCPP) as part of the sixth Coupled Model Intercomparison Project (CMIP6). We describe the system and evaluate its baseline, reanalysis and prediction performance.
Maria Sand, Bjørn H. Samset, Gunnar Myhre, Jonas Gliß, Susanne E. Bauer, Huisheng Bian, Mian Chin, Ramiro Checa-Garcia, Paul Ginoux, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Philippe Le Sager, Marianne T. Lund, Hitoshi Matsui, Twan van Noije, Dirk J. L. Olivié, Samuel Remy, Michael Schulz, Philip Stier, Camilla W. Stjern, Toshihiko Takemura, Kostas Tsigaridis, Svetlana G. Tsyro, and Duncan Watson-Parris
Atmos. Chem. Phys., 21, 15929–15947, https://doi.org/10.5194/acp-21-15929-2021, https://doi.org/10.5194/acp-21-15929-2021, 2021
Short summary
Short summary
Absorption of shortwave radiation by aerosols can modify precipitation and clouds but is poorly constrained in models. A total of 15 different aerosol models from AeroCom phase III have reported total aerosol absorption, and for the first time, 11 of these models have reported in a consistent experiment the contributions to absorption from black carbon, dust, and organic aerosol. Here, we document the model diversity in aerosol absorption.
Tao Tang, Drew Shindell, Yuqiang Zhang, Apostolos Voulgarakis, Jean-Francois Lamarque, Gunnar Myhre, Gregory Faluvegi, Bjørn H. Samset, Timothy Andrews, Dirk Olivié, Toshihiko Takemura, and Xuhui Lee
Atmos. Chem. Phys., 21, 13797–13809, https://doi.org/10.5194/acp-21-13797-2021, https://doi.org/10.5194/acp-21-13797-2021, 2021
Short summary
Short summary
Previous studies showed that black carbon (BC) could warm the surface with decreased incoming radiation. With climate models, we found that the surface energy redistribution plays a more crucial role in surface temperature compared with other forcing agents. Though BC could reduce the surface heating, the energy dissipates less efficiently, which is manifested by reduced convective and evaporative cooling, thereby warming the surface.
Ramiro Checa-Garcia, Yves Balkanski, Samuel Albani, Tommi Bergman, Ken Carslaw, Anne Cozic, Chris Dearden, Beatrice Marticorena, Martine Michou, Twan van Noije, Pierre Nabat, Fiona M. O'Connor, Dirk Olivié, Joseph M. Prospero, Philippe Le Sager, Michael Schulz, and Catherine Scott
Atmos. Chem. Phys., 21, 10295–10335, https://doi.org/10.5194/acp-21-10295-2021, https://doi.org/10.5194/acp-21-10295-2021, 2021
Short summary
Short summary
Thousands of tons of dust are emitted into the atmosphere every year, producing important impacts on the Earth system. However, current global climate models are not yet able to reproduce dust emissions, transport and depositions with the desirable accuracy. Our study analyses five different Earth system models to report aspects to be improved to reproduce better available observations, increase the consistency between models and therefore decrease the current uncertainties.
Josué Bock, Martine Michou, Pierre Nabat, Manabu Abe, Jane P. Mulcahy, Dirk J. L. Olivié, Jörg Schwinger, Parvadha Suntharalingam, Jerry Tjiputra, Marco van Hulten, Michio Watanabe, Andrew Yool, and Roland Séférian
Biogeosciences, 18, 3823–3860, https://doi.org/10.5194/bg-18-3823-2021, https://doi.org/10.5194/bg-18-3823-2021, 2021
Short summary
Short summary
In this study we analyse surface ocean dimethylsulfide (DMS) concentration and flux to the atmosphere from four CMIP6 Earth system models over the historical and ssp585 simulations.
Our analysis of contemporary (1980–2009) climatologies shows that models better reproduce observations in mid to high latitudes. The models disagree on the sign of the trend of the global DMS flux from 1980 onwards. The models agree on a positive trend of DMS over polar latitudes following sea-ice retreat dynamics.
James Keeble, Birgit Hassler, Antara Banerjee, Ramiro Checa-Garcia, Gabriel Chiodo, Sean Davis, Veronika Eyring, Paul T. Griffiths, Olaf Morgenstern, Peer Nowack, Guang Zeng, Jiankai Zhang, Greg Bodeker, Susannah Burrows, Philip Cameron-Smith, David Cugnet, Christopher Danek, Makoto Deushi, Larry W. Horowitz, Anne Kubin, Lijuan Li, Gerrit Lohmann, Martine Michou, Michael J. Mills, Pierre Nabat, Dirk Olivié, Sungsu Park, Øyvind Seland, Jens Stoll, Karl-Hermann Wieners, and Tongwen Wu
Atmos. Chem. Phys., 21, 5015–5061, https://doi.org/10.5194/acp-21-5015-2021, https://doi.org/10.5194/acp-21-5015-2021, 2021
Short summary
Short summary
Stratospheric ozone and water vapour are key components of the Earth system; changes to both have important impacts on global and regional climate. We evaluate changes to these species from 1850 to 2100 in the new generation of CMIP6 models. There is good agreement between the multi-model mean and observations, although there is substantial variation between the individual models. The future evolution of both ozone and water vapour is strongly dependent on the assumed future emissions scenario.
Yanan Zhao, Cathleen Schlundt, Dennis Booge, and Hermann W. Bange
Biogeosciences, 18, 2161–2179, https://doi.org/10.5194/bg-18-2161-2021, https://doi.org/10.5194/bg-18-2161-2021, 2021
Short summary
Short summary
We present a unique and comprehensive time-series study of biogenic sulfur compounds in the southwestern Baltic Sea, from 2009 to 2018. Dimethyl sulfide is one of the key players regulating global climate change, as well as dimethylsulfoniopropionate and dimethyl sulfoxide. Their decadal trends did not follow increasing temperature but followed some algae group abundances at the Boknis Eck Time Series Station.
Josefine Maas, Susann Tegtmeier, Yue Jia, Birgit Quack, Jonathan V. Durgadoo, and Arne Biastoch
Atmos. Chem. Phys., 21, 4103–4121, https://doi.org/10.5194/acp-21-4103-2021, https://doi.org/10.5194/acp-21-4103-2021, 2021
Short summary
Short summary
Cooling-water disinfection at coastal power plants is a known source of atmospheric bromoform. A large source of anthropogenic bromoform is the industrial regions in East Asia. In current bottom-up flux estimates, these anthropogenic emissions are missing, underestimating the global air–sea flux of bromoform. With transport simulations, we show that by including anthropogenic bromoform from cooling-water treatment, the bottom-up flux estimates significantly improve in East and Southeast Asia.
Hanna Lee, Helene Muri, Altug Ekici, Jerry Tjiputra, and Jörg Schwinger
Earth Syst. Dynam., 12, 313–326, https://doi.org/10.5194/esd-12-313-2021, https://doi.org/10.5194/esd-12-313-2021, 2021
Short summary
Short summary
We assess how three different geoengineering methods using aerosol affect land ecosystem carbon storage. Changes in temperature and precipitation play a large role in vegetation carbon uptake and storage, but our results show that increased levels of CO2 also play a considerable role. We show that there are unforeseen regional consequences under geoengineering applications, and these consequences should be taken into account in future climate policies before implementing them.
Claudia Tebaldi, Kevin Debeire, Veronika Eyring, Erich Fischer, John Fyfe, Pierre Friedlingstein, Reto Knutti, Jason Lowe, Brian O'Neill, Benjamin Sanderson, Detlef van Vuuren, Keywan Riahi, Malte Meinshausen, Zebedee Nicholls, Katarzyna B. Tokarska, George Hurtt, Elmar Kriegler, Jean-Francois Lamarque, Gerald Meehl, Richard Moss, Susanne E. Bauer, Olivier Boucher, Victor Brovkin, Young-Hwa Byun, Martin Dix, Silvio Gualdi, Huan Guo, Jasmin G. John, Slava Kharin, YoungHo Kim, Tsuyoshi Koshiro, Libin Ma, Dirk Olivié, Swapna Panickal, Fangli Qiao, Xinyao Rong, Nan Rosenbloom, Martin Schupfner, Roland Séférian, Alistair Sellar, Tido Semmler, Xiaoying Shi, Zhenya Song, Christian Steger, Ronald Stouffer, Neil Swart, Kaoru Tachiiri, Qi Tang, Hiroaki Tatebe, Aurore Voldoire, Evgeny Volodin, Klaus Wyser, Xiaoge Xin, Shuting Yang, Yongqiang Yu, and Tilo Ziehn
Earth Syst. Dynam., 12, 253–293, https://doi.org/10.5194/esd-12-253-2021, https://doi.org/10.5194/esd-12-253-2021, 2021
Short summary
Short summary
We present an overview of CMIP6 ScenarioMIP outcomes from up to 38 participating ESMs according to the new SSP-based scenarios. Average temperature and precipitation projections according to a wide range of forcings, spanning a wider range than the CMIP5 projections, are documented as global averages and geographic patterns. Times of crossing various warming levels are computed, together with benefits of mitigation for selected pairs of scenarios. Comparisons with CMIP5 are also discussed.
Gillian D. Thornhill, William J. Collins, Ryan J. Kramer, Dirk Olivié, Ragnhild B. Skeie, Fiona M. O'Connor, Nathan Luke Abraham, Ramiro Checa-Garcia, Susanne E. Bauer, Makoto Deushi, Louisa K. Emmons, Piers M. Forster, Larry W. Horowitz, Ben Johnson, James Keeble, Jean-Francois Lamarque, Martine Michou, Michael J. Mills, Jane P. Mulcahy, Gunnar Myhre, Pierre Nabat, Vaishali Naik, Naga Oshima, Michael Schulz, Christopher J. Smith, Toshihiko Takemura, Simone Tilmes, Tongwen Wu, Guang Zeng, and Jie Zhang
Atmos. Chem. Phys., 21, 853–874, https://doi.org/10.5194/acp-21-853-2021, https://doi.org/10.5194/acp-21-853-2021, 2021
Short summary
Short summary
This paper is a study of how different constituents in the atmosphere, such as aerosols and gases like methane and ozone, affect the energy balance in the atmosphere. Different climate models were run using the same inputs to allow an easy comparison of the results and to understand where the models differ. We found the effect of aerosols is to reduce warming in the atmosphere, but this effect varies between models. Reactions between gases are also important in affecting climate.
Jonas Gliß, Augustin Mortier, Michael Schulz, Elisabeth Andrews, Yves Balkanski, Susanne E. Bauer, Anna M. K. Benedictow, Huisheng Bian, Ramiro Checa-Garcia, Mian Chin, Paul Ginoux, Jan J. Griesfeller, Andreas Heckel, Zak Kipling, Alf Kirkevåg, Harri Kokkola, Paolo Laj, Philippe Le Sager, Marianne Tronstad Lund, Cathrine Lund Myhre, Hitoshi Matsui, Gunnar Myhre, David Neubauer, Twan van Noije, Peter North, Dirk J. L. Olivié, Samuel Rémy, Larisa Sogacheva, Toshihiko Takemura, Kostas Tsigaridis, and Svetlana G. Tsyro
Atmos. Chem. Phys., 21, 87–128, https://doi.org/10.5194/acp-21-87-2021, https://doi.org/10.5194/acp-21-87-2021, 2021
Short summary
Short summary
Simulated aerosol optical properties as well as the aerosol life cycle are investigated for 14 global models participating in the AeroCom initiative. Considerable diversity is found in the simulated aerosol species emissions and lifetimes, also resulting in a large diversity in the simulated aerosol mass, composition, and optical properties. A comparison with observations suggests that, on average, current models underestimate the direct effect of aerosol on the atmosphere radiation budget.
Kine Onsum Moseid, Michael Schulz, Trude Storelvmo, Ingeborg Rian Julsrud, Dirk Olivié, Pierre Nabat, Martin Wild, Jason N. S. Cole, Toshihiko Takemura, Naga Oshima, Susanne E. Bauer, and Guillaume Gastineau
Atmos. Chem. Phys., 20, 16023–16040, https://doi.org/10.5194/acp-20-16023-2020, https://doi.org/10.5194/acp-20-16023-2020, 2020
Short summary
Short summary
In this study we compare solar radiation at the surface from observations and Earth system models from 1961 to 2014. We find that the models do not reproduce the so-called
global dimmingas found in observations. Only model experiments with anthropogenic aerosol emissions display any dimming at all. The discrepancies between observations and models are largest in China, which we suggest is in part due to erroneous aerosol precursor emission inventories in the emission dataset used for CMIP6.
Øyvind Seland, Mats Bentsen, Dirk Olivié, Thomas Toniazzo, Ada Gjermundsen, Lise Seland Graff, Jens Boldingh Debernard, Alok Kumar Gupta, Yan-Chun He, Alf Kirkevåg, Jörg Schwinger, Jerry Tjiputra, Kjetil Schanke Aas, Ingo Bethke, Yuanchao Fan, Jan Griesfeller, Alf Grini, Chuncheng Guo, Mehmet Ilicak, Inger Helene Hafsahl Karset, Oskar Landgren, Johan Liakka, Kine Onsum Moseid, Aleksi Nummelin, Clemens Spensberger, Hui Tang, Zhongshi Zhang, Christoph Heinze, Trond Iversen, and Michael Schulz
Geosci. Model Dev., 13, 6165–6200, https://doi.org/10.5194/gmd-13-6165-2020, https://doi.org/10.5194/gmd-13-6165-2020, 2020
Short summary
Short summary
The second version of the coupled Norwegian Earth System Model (NorESM2) is presented and evaluated. The temperature and precipitation patterns has improved compared to NorESM1. The model reaches present-day warming levels to within 0.2 °C of observed temperature but with a delayed warming during the late 20th century. Under the four scenarios (SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5), the warming in the period of 2090–2099 compared to 1850–1879 reaches 1.3, 2.2, 3.1, and 3.9 K.
Steven T. Turnock, Robert J. Allen, Martin Andrews, Susanne E. Bauer, Makoto Deushi, Louisa Emmons, Peter Good, Larry Horowitz, Jasmin G. John, Martine Michou, Pierre Nabat, Vaishali Naik, David Neubauer, Fiona M. O'Connor, Dirk Olivié, Naga Oshima, Michael Schulz, Alistair Sellar, Sungbo Shim, Toshihiko Takemura, Simone Tilmes, Kostas Tsigaridis, Tongwen Wu, and Jie Zhang
Atmos. Chem. Phys., 20, 14547–14579, https://doi.org/10.5194/acp-20-14547-2020, https://doi.org/10.5194/acp-20-14547-2020, 2020
Short summary
Short summary
A first assessment is made of the historical and future changes in air pollutants from models participating in the 6th Coupled Model Intercomparison Project (CMIP6). Substantial benefits to future air quality can be achieved in future scenarios that implement measures to mitigate climate and involve reductions in air pollutant emissions, particularly methane. However, important differences are shown between models in the future regional projection of air pollutants under the same scenario.
Augustin Mortier, Jonas Gliß, Michael Schulz, Wenche Aas, Elisabeth Andrews, Huisheng Bian, Mian Chin, Paul Ginoux, Jenny Hand, Brent Holben, Hua Zhang, Zak Kipling, Alf Kirkevåg, Paolo Laj, Thibault Lurton, Gunnar Myhre, David Neubauer, Dirk Olivié, Knut von Salzen, Ragnhild Bieltvedt Skeie, Toshihiko Takemura, and Simone Tilmes
Atmos. Chem. Phys., 20, 13355–13378, https://doi.org/10.5194/acp-20-13355-2020, https://doi.org/10.5194/acp-20-13355-2020, 2020
Short summary
Short summary
We present a multiparameter analysis of the aerosol trends over the last 2 decades in the different regions of the world. In most of the regions, ground-based observations show a decrease in aerosol content in both the total atmospheric column and at the surface. The use of climate models, assessed against these observations, reveals however an increase in the total aerosol load, which is not seen with the sole use of observation due to partial coverage in space and time.
Cited articles
Agus, E., Voutchkov, N., and Sedlak, D. L.: Disinfection by-products and their potential impact on the quality of water produced by desalination systems: A literature review, Desalination, 237, 214–237, https://doi.org/10.1016/j.desal.2007.11.059, 2009.
Assmann, K. M., Bentsen, M., Segschneider, J., and Heinze, C.: An isopycnic ocean carbon cycle model, Geosci. Model Dev., 3, 143–167, https://doi.org/10.5194/gmd-3-143-2010, 2010.
Bates, N. R. and Merlivat, L.: The influence of short-term wind variability on air-sea CO exchange, Geophys. Res. Lett., 28, 3281–3284, https://doi.org/10.1029/2001gl012897, 2001.
Bentsen, M., Bethke, I., Debernard, J. B., Iversen, T., Kirkevåg, A., Seland, Ø., Drange, H., Roelandt, C., Seierstad, I. A., Hoose, C., and Kristjánsson, J. E.: The Norwegian Earth System Model, NorESM1-M – Part 1: Description and basic evaluation of the physical climate, Geosci. Model Dev., 6, 687–720, https://doi.org/10.5194/gmd-6-687-2013, 2013.
Booge, D. and Quack, B.: Bromoform observations in the HalOcAt database, Zenodo [data set], https://doi.org/10.5281/zenodo.11919150, 2024.
Butler, J. H., King, D. B., Lobert, J. M., Montzka, S. A., Yvon-Lewis, S. A., Hall, B. D., Warwick, N. J., Mondeel, D. J., Aydin, M., and Elkins, J. W.: Oceanic distributions and emissions of short-lived halocarbons, Global Biogeochem. Cy., 21, 1023 10.1029/2006gb002732, 2007.
Carpenter, L. J. and Liss, P. S.: On temperate sources of bromoform and other reactive organic bromine gases, J. Geophys. Res.-Atmos., 105, 20539–20547, https://doi.org/10.1029/2000jd900242, 2000.
Danabasoglu, G., Lamarque, J. F., Bacmeister, J., Bailey, D. A., DuVivier, A. K., Edwards, J., Emmons, L. K., Fasullo, J., Garcia, R., Gettelman, A., Hannay, C., Holland, M. M., Large, W. G., Lauritzen, P. H., Lawrence, D. M., Lenaerts, J. T. M., Lindsay, K., Lipscomb, W. H., Mills, M. J., Neale, R., Oleson, K. W., Otto-Bliesner, B., Phillips, A. S., Sacks, W., Tilmes, S., van Kampenhout, L., Vertenstein, M., Bertini, A., Dennis, J., Deser, C., Fischer, C., Fox-Kemper, B., Kay, J. E., Kinnison, D., Kushner, P. J., Larson, V. E., Long, M. C., Mickelson, S., Moore, J. K., Nienhouse, E., Polvani, L., Rasch, P. J., and Strand, W. G.: The Community Earth System Model Version 2 (CESM2), J. Adv. Model. Earth Syst., 12, e2019MS001916 https://doi.org/10.1029/2019MS001916, 2020.
Daniel, J. S., Solomon, S., Portmann, R. W., and Garcia, R. R.: Stratospheric ozone destruction: The importance of bromine relative to chlorine, J. Geophys. Res.-Atmos., 104, 23871–23880, https://doi.org/10.1029/1999jd900381, 1999.
Dorf, M., Butler, J. H., Butz, A., Camy-Peyret, C., Chipperfield, M. P., Kritten, L., Montzka, S. A., Simmes, B., Weidner, F., and Pfeilsticker, K.: Long-term observations of stratospheric bromine reveal slow down in growth, Geophys. Res. Lett., 33, L24803 https://doi.org/10.1029/2006gl027714, 2006.
Fiehn, A., Quack, B., Stemmler, I., Ziska, F., and Krüger, K.: Importance of seasonally resolved oceanic emissions for bromoform delivery from the tropical Indian Ocean and west Pacific to the stratosphere, Atmos. Chem. Phys., 18, 11973–11990, https://doi.org/10.5194/acp-18-11973-2018, 2018.
Fuhlbrügge, S., Krüger, K., Quack, B., Atlas, E., Hepach, H., and Ziska, F.: Impact of the marine atmospheric boundary layer conditions on VSLS abundances in the eastern tropical and subtropical North Atlantic Ocean, Atmos. Chem. Phys., 13, 6345–6357, https://doi.org/10.5194/acp-13-6345-2013, 2013.
Fuhlbrügge, S., Quack, B., Tegtmeier, S., Atlas, E., Hepach, H., Shi, Q., Raimund, S., and Krüger, K.: The contribution of oceanic halocarbons to marine and free tropospheric air over the tropical West Pacific, Atmos. Chem. Phys., 16, 7569–7585, https://doi.org/10.5194/acp-16-7569-2016, 2016.
Gebhardt, S.: Biogenic emission of halocarbons, Mainz, Univ., Diss., 2008, https://doi.org/10.25358/openscience-2211, 2008.
Gettelman, A., Mills, M. J., Kinnison, D. E., Garcia, R. R., Smith, A. K., Marsh, D. R., Tilmes, S., Vitt, F., Bardeen, C. G., McInerny, J., Liu, H. L., Solomon, S. C., Polvani, L. M., Emmons, L. K., Lamarque, J. F., Richter, J. H., Glanville, A. S., Bacmeister, J. T., Phillips, A. S., Neale, R. B., Simpson, I. R., DuVivier, A. K., Hodzic, A., and Randel, W. J.: The Whole Atmosphere Community Climate Model Version 6 (WACCM6), J. Geophys. Res.-Atmos., 124, 12380–12403, https://doi.org/10.1029/2019jd030943, 2019.
Gschwend, P. M., Macfarlane, J. K., and Newman, K. A.: Volatile halogenated organic compounds released to seawater from temperate marine macroalgae, Science, 227, 1033–1035, doi10.1126/science.227.4690.1033, 1985.
Hense, I. and Quack, B.: Modelling the vertical distribution of bromoform in the upper water column of the tropical Atlantic Ocean, Biogeosciences, 6, 535–544, https://doi.org/10.5194/bg-6-535-2009, 2009.
Hepach, H., Quack, B., Tegtmeier, S., Engel, A., Bracher, A., Fuhlbrügge, S., Galgani, L., Atlas, E. L., Lampel, J., Frieß, U., and Krüger, K.: Biogenic halocarbons from the Peruvian upwelling region as tropospheric halogen source, Atmos. Chem. Phys., 16, 12219–12237, https://doi.org/10.5194/acp-16-12219-2016, 2016.
Hossaini, R., Chipperfield, M. P., Montzka, S. A., Rap, A., Dhomse, S., and Feng, W.: Efficiency of short-lived halogens at influencing climate through depletion of stratospheric ozone, Nat. Geosci., 8, 186–190, https://doi.org/10.1038/Ngeo2363, 2015.
Jia, Y., Hahn, J., Quack, B., Jones, E., Brehon, M., and Tegtmeier, S.: Anthropogenic Bromoform at the Extratropical Tropopause, Geophys. Res. Lett., 50, e2023GL102894, https://doi.org/10.1029/2023GL102894, 2023.
Kurihara, M., Iseda, M., Ioriya, T., Horimoto, N., Kanda, J., Ishimaru, T., Yamaguchi, Y., and Hashimoto, S.: Brominated methane compounds and isoprene in surface seawater of Sagami Bay: Concentrations, fluxes, and relationships with phytoplankton assemblages, Mar. Chem., 134, 71–79, https://doi.org/10.1016/j.marchem.2012.04.001, 2012.
Laube, J. C., Tegtmeier, S., Fernandez, R. P., Harrison, J., Hu, L., Krummel, P., Mahieu, E., Park, S., and Western, L.: Update on Ozone-Depleting Substances (ODSs) and Other Gases of Interest to the Montreal Protocol, 978-9914-733-97-6, 2023.
Law, K., Sturges, W., Blake, D., Blake, N., Burkholder, J., Butler, J., Cox, R., Haynes, P., Ko, M., and Kreher, K.: Halogenated very short-lived substances, Chapter 2 in: Scientific Assessment of Ozone Depletion: 2006, Global Ozone Research and Monitoring Project–Report No. 50, World Meteorological Organization, Geneva, Switzerland, 572, 2007.
Lennartz, S. T., Krysztofiak, G., Marandino, C. A., Sinnhuber, B.-M., Tegtmeier, S., Ziska, F., Hossaini, R., Krüger, K., Montzka, S. A., Atlas, E., Oram, D. E., Keber, T., Bönisch, H., and Quack, B.: Modelling marine emissions and atmospheric distributions of halocarbons and dimethyl sulfide: the influence of prescribed water concentration vs. prescribed emissions, Atmos. Chem. Phys., 15, 11753–11772, https://doi.org/10.5194/acp-15-11753-2015, 2015.
Liang, Q., Stolarski, R. S., Kawa, S. R., Nielsen, J. E., Douglass, A. R., Rodriguez, J. M., Blake, D. R., Atlas, E. L., and Ott, L. E.: Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2, Atmos. Chem. Phys., 10, 2269–2286, https://doi.org/10.5194/acp-10-2269-2010, 2010.
Maas, J., Tegtmeier, S., Jia, Y., Quack, B., Durgadoo, J. V., and Biastoch, A.: Simulations of anthropogenic bromoform indicate high emissions at the coast of East Asia, Atmos. Chem. Phys., 21, 4103–4121, https://doi.org/10.5194/acp-21-4103-2021, 2021.
Maier-Reimer, E.: Geochemical cycles in an ocean general circulation model. Preindustrial tracer distributions, Global Biogeochem. Cy., 7, 645–677, https://doi.org/10.1029/93gb01355, 2012.
Masson-Delmotte, V., Zhai, P., Pirani, A., Connors, S. L., Péan, C., Berger, S., Caud, N., Chen, Y., Goldfarb, L., Gomis, M. I., Huang, M., Leitzell, K., Lonnoy, E., Matthews, J. B. R., Maycock, T. K., Waterfield, T., Yelekçi, O., Yu, R., Zhou, B., and Ipcc: Annex I: Observational Products, in: Climate Change 2021 – The Physical Science Basis, Cambridge University Press, Cambridge, United Kingdom and New York, NY, USA, 2061–2086, https://doi.org/10.1017/9781009157896.015, 2023.
Montzka, S. A., Reimann, S., Engel, A., Kruger, K., Sturges, W. T., Blake, D., Dorf, M., Fraser, P., Froidevaux, L., and Jucks, K.: Ozone-depleting substances (ODSs) and related chemicals, Chap. 1 in Scientific Assessment of Ozone Depletion: 2010, Global Ozone Research and Monitoring Project-Report No. 52, 526 pp., Geneva, Switzerland, 2011.
Moore, R. M., Geen, C. E., and Tait, V. K.: Determination of Henry's Law constants for a suite of naturally occurring halogenated methanes in seawater, Chemosphere, 30, 1183–1191, https://doi.org/10.1016/0045-6535(95)00009-w, 1995.
Moore, R. M., Webb, M., Tokarczyk, R., and Wever, R.: Bromoperoxidase and iodoperoxidase enzymes and production of halogenated methanes in marine diatom cultures, J. Geophys. Res.-Oceans, 101, 20899–20908, https://doi.org/10.1029/96jc01248, 1996.
Navarro, M. A., Atlas, E. L., Saiz-Lopez, A., Rodriguez-Lloveras, X., Kinnison, D. E., Lamarque, J. F., Tilmes, S., Filus, M., Harris, N. R., Meneguz, E., Ashfold, M. J., Manning, A. J., Cuevas, C. A., Schauffler, S. M., and Donets, V.: Airborne measurements of organic bromine compounds in the Pacific tropical tropopause layer, P. Natl. Acad. Sci. USA, 112, 13789–13793, https://doi.org/10.1073/pnas.1511463112, 2015.
Nightingale, P. D., Malin, G., Law, C. S., Watson, A. J., Liss, P. S., Liddicoat, M. I., Boutin, J., and Upstill-Goddard, R. C.: In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cy., 14, 373–387, https://doi.org/10.1029/1999gb900091, 2000.
Ordóñez, C., Lamarque, J.-F., Tilmes, S., Kinnison, D. E., Atlas, E. L., Blake, D. R., Sousa Santos, G., Brasseur, G., and Saiz-Lopez, A.: Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423–1447, https://doi.org/10.5194/acp-12-1423-2012, 2012.
Papanastasiou, D. K., McKeen, S. A., and Burkholder, J. B.: The very short-lived ozone depleting substance CHBr3 (bromoform): revised UV absorption spectrum, atmospheric lifetime and ozone depletion potential, Atmos. Chem. Phys., 14, 3017–3025, https://doi.org/10.5194/acp-14-3017-2014, 2014.
Quack, B. and Wallace, D. W. R.: Air-sea flux of bromoform: Controls, rates, and implications, Global Biogeochem. Cy., 17, 1023, https://doi.org/10.1029/2002gb001890, 2003.
Quack, B., Atlas, E., Petrick, G., Stroud, V., Schauffler, S., and Wallace, D. W. R.: Oceanic bromoform sources for the tropical atmosphere, Geophys. Res. Lett., 31, L23s05 https://doi.org/10.1029/2004gl020597, 2004.
Roy, R.: Short-term variability in halocarbons in relation to phytoplankton pigments in coastal waters of the central eastern Arabian Sea, Est. Coastal Shelf Sci., 88, 311–321, https://doi.org/10.1016/j.ecss.2010.04.011, 2010.
Saiz-Lopez, A., Fernandez, R. P., Li, Q., Cuevas, C. A., Fu, X., Kinnison, D. E., Tilmes, S., Mahajan, A. S., Gomez Martin, J. C., Iglesias-Suarez, F., Hossaini, R., Plane, J. M. C., Myhre, G., and Lamarque, J. F.: Natural short-lived halogens exert an indirect cooling effect on climate, Nature, 618, 967–973, https://doi.org/10.1038/s41586-023-06119-z, 2023.
Sala, S., Bönisch, H., Keber, T., Oram, D. E., Mills, G., and Engel, A.: Deriving an atmospheric budget of total organic bromine using airborne in situ measurements from the western Pacific area during SHIVA, Atmos. Chem. Phys., 14, 6903–6923, https://doi.org/10.5194/acp-14-6903-2014, 2014.
Salawitch, R. J.: Atmospheric chemistry: biogenic bromine, Nature, 439, 275–277, https://doi.org/10.1038/439275a, 2006.
Seland, Ø., Bentsen, M., Olivié, D., Toniazzo, T., Gjermundsen, A., Graff, L. S., Debernard, J. B., Gupta, A. K., He, Y.-C., Kirkevåg, A., Schwinger, J., Tjiputra, J., Aas, K. S., Bethke, I., Fan, Y., Griesfeller, J., Grini, A., Guo, C., Ilicak, M., Karset, I. H. H., Landgren, O., Liakka, J., Moseid, K. O., Nummelin, A., Spensberger, C., Tang, H., Zhang, Z., Heinze, C., Iversen, T., and Schulz, M.: Overview of the Norwegian Earth System Model (NorESM2) and key climate response of CMIP6 DECK, historical, and scenario simulations, Geosci. Model Dev., 13, 6165–6200, https://doi.org/10.5194/gmd-13-6165-2020, 2020.
Sinnhuber, B.-M., Sheode, N., Sinnhuber, M., Chipperfield, M. P., and Feng, W.: The contribution of anthropogenic bromine emissions to past stratospheric ozone trends: a modelling study, Atmos. Chem. Phys., 9, 2863–2871, https://doi.org/10.5194/acp-9-2863-2009, 2009.
Stemmler, I., Hense, I., and Quack, B.: Marine sources of bromoform in the global open ocean – global patterns and emissions, Biogeosciences, 12, 1967–1981, https://doi.org/10.5194/bg-12-1967-2015, 2015.
Tegtmeier, S., Atlas, E., Quack, B., Ziska, F., and Krüger, K.: Variability and past long-term changes of brominated very short-lived substances at the tropical tropopause, Atmos. Chem. Phys., 20, 7103–7123, https://doi.org/10.5194/acp-20-7103-2020, 2020.
Tjiputra, J. F., Assmann, K., Bentsen, M., Bethke, I., Otterå, O. H., Sturm, C., and Heinze, C.: Bergen Earth system model (BCM-C): model description and regional climate-carbon cycle feedbacks assessment, Geosci. Model Dev., 3, 123–141, https://doi.org/10.5194/gmd-3-123-2010, 2010.
Tjiputra, J. F., Roelandt, C., Bentsen, M., Lawrence, D. M., Lorentzen, T., Schwinger, J., Seland, Ø., and Heinze, C.: Evaluation of the carbon cycle components in the Norwegian Earth System Model (NorESM), Geosci. Model Dev., 6, 301–325, https://doi.org/10.5194/gmd-6-301-2013, 2013.
Tjiputra, J. F., Schwinger, J., Bentsen, M., Morée, A. L., Gao, S., Bethke, I., Heinze, C., Goris, N., Gupta, A., He, Y.-C., Olivié, D., Seland, Ø., and Schulz, M.: Ocean biogeochemistry in the Norwegian Earth System Model version 2 (NorESM2), Geosci. Model Dev., 13, 2393–2431, https://doi.org/10.5194/gmd-13-2393-2020, 2020.
Tokarczyk, R. and Moore, R. M.: Production of Volatile Organohalogens by Phytoplankton Cultures, Geophys. Res. Lett., 21, 285–288, https://doi.org/10.1029/94gl00009, 1994.
Villamayor, J., Iglesias-Suarez, F., Cuevas, C. A., Fernandez, R. P., Li, Q. Y., Abalos, M., Hossaini, R., Chipperfield, M. P., Kinnison, D. E., Tilmes, S., Lamarque, J. F., and Saiz-Lopez, A.: Very short-lived halogens amplify ozone depletion trends in the tropical lower stratosphere, Nat. Clim. Change, 13, 554–560, https://doi.org/10.1038/s41558-023-01671-y, 2023.
Wang, S. Y., Kinnison, D., Montzka, S. A., Apel, E. C., Hornbrook, R. S., Hills, A. J., Blake, D. R., Barletta, B., Meinardi, S., Sweeney, C., Moore, F., Long, M., Saiz-Lopez, A., Fernandez, R. P., Tilmes, S., Emmons, L. K., and Lamarque, J. F.: Ocean Biogeochemistry Control on the Marine Emissions of Brominated Very Short-Lived Ozone-Depleting Substances: A Machine-Learning Approach, J. Geophys. Res.-Atmos., 124, 12319–12339, https://doi.org/10.1029/2019jd031288, 2019.
Wanninkhof, R.: The Impact of Different Gas Exchange Formulations and Wind Speed Products on Global Air-Sea CO2 Fluxes, in: Transport at the Air-Sea Interface, edited by: Garbe, C. S., Handler, R. A., and Jähne, B., Environmental Science and Engineering, Springer Berlin Heidelberg, Berlin, Heidelberg, 1–23, https://doi.org/10.1007/978-3-540-36906-6_1, 2007.
Warwick, N. J., Pyle, J. A., Carver, G. D., Yang, X., Savage, N. H., O'Connor, F. M., and Cox, R. A.: Global modeling of biogenic bromocarbons, J. Geophys. Res.-Atmos., 111, D24305, https://doi.org/10.1029/2006jd007264, 2006.
Washington, J. W.: Hydrolysis Rates of Dissolved Volatile Organic-Compounds – Principles, Temperature Effects and Literature-Review, Ground Water, 33, 415–424, https://doi.org/10.1111/j.1745-6584.1995.tb00298.x, 1995.
Yang, M. X., Bell, T. G., Bidlot, J. R., Blomquist, B. W., Butterworth, B. J., Dong, Y. X., Fairall, C. W., Landwehr, S., Marandino, C. A., Miller, S. D., Saltzman, E. S., and Zavarsky, A.: Global Synthesis of Air-Sea CO Transfer Velocity Estimates From Ship-Based Eddy Covariance Measurements, Front. Mar. Sci., 9, 826421, https://doi.org/10.3389/fmars.2022.826421, 2022.
Ziska, F., Quack, B., Abrahamsson, K., Archer, S. D., Atlas, E., Bell, T., Butler, J. H., Carpenter, L. J., Jones, C. E., Harris, N. R. P., Hepach, H., Heumann, K. G., Hughes, C., Kuss, J., Krüger, K., Liss, P., Moore, R. M., Orlikowska, A., Raimund, S., Reeves, C. E., Reifenhäuser, W., Robinson, A. D., Schall, C., Tanhua, T., Tegtmeier, S., Turner, S., Wang, L., Wallace, D., Williams, J., Yamamoto, H., Yvon-Lewis, S., and Yokouchi, Y.: Global sea-to-air flux climatology for bromoform, dibromomethane and methyl iodide, Atmos. Chem. Phys., 13, 8915–8934, https://doi.org/10.5194/acp-13-8915-2013, 2013.
Short summary
Oceanic bromoform, produced by algae, is an important precursor of atmospheric bromine, highlighting the importance of implementing these emissions in climate models. The simulated mean oceanic concentrations align well with observations, while the mean atmospheric values are lower than the observed ones. Modelled annual mean emissions mostly occur from the sea to the air and are driven by oceanic concentrations, sea surface temperature, and wind speed, which depend on season and location.
Oceanic bromoform, produced by algae, is an important precursor of atmospheric bromine,...
Altmetrics
Final-revised paper
Preprint