Articles | Volume 13, issue 2
https://doi.org/10.5194/esd-13-703-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
https://doi.org/10.5194/esd-13-703-2022
© Author(s) 2022. This work is distributed under
the Creative Commons Attribution 4.0 License.
the Creative Commons Attribution 4.0 License.
CO2 surface variability: from the stratosphere or not?
Earth System Science Department, University of California Irvine, Irvine, CA 92617, USA
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Jinbo Xie, Qi Tang, Michael Prather, Jadwiga Richter, and Shixuan Zhang
Atmos. Chem. Phys., 25, 9315–9333, https://doi.org/10.5194/acp-25-9315-2025, https://doi.org/10.5194/acp-25-9315-2025, 2025
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Analysis of the interaction between the climate and ozone in the stratosphere is complicated by the inability of climate models to simulate the quasi-biennial oscillation (QBO) – an important climate mode in the stratosphere. We use a set of model simulations that realistically simulate QBO and a novel ozone diagnostic tool to separate temperature- and circulation-driven QBO impacts. These are important for diagnosing model–model differences in QBO–ozone responses for climate projections.
Paul T. Griffiths, Laura J. Wilcox, Robert J. Allen, Vaishali Naik, Fiona M. O'Connor, Michael Prather, Alex Archibald, Florence Brown, Makoto Deushi, William Collins, Stephanie Fiedler, Naga Oshima, Lee T. Murray, Bjørn H. Samset, Chris Smith, Steven Turnock, Duncan Watson-Parris, and Paul J. Young
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The Aerosol Chemistry Model Intercomparison Project (AerChemMIP) aimed to quantify the climate and air quality impacts of aerosols and chemically reactive gases. We review its contribution to AR6 (Sixth Assessment Report of the Intergovernmental Panel on Climate Change) and the wider understanding of the role of these species in climate and climate change. We identify challenges and provide recommendations to improve the utility and uptake of climate model data, detailed summary tables of CMIP6 models, experiments, and emergent diagnostics.
Clara Orbe, Alison Ming, Gabriel Chiodo, Michael Prather, Mohamadou Diallo, Qi Tang, Andreas Chrysanthou, Hiroaki Naoe, Xin Zhou, Irina Thaler, Dillon Elsbury, Ewa Bednarz, Jonathon S. Wright, Aaron Match, Shingo Watanabe, James Anstey, Tobias Kerzenmacher, Stefan Versick, Marion Marchand, Feng Li, and James Keeble
EGUsphere, https://doi.org/10.5194/egusphere-2025-2761, https://doi.org/10.5194/egusphere-2025-2761, 2025
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The quasi-biennial oscillation (QBO) is the main source of wind fluctuations in the tropical stratosphere, which can couple to surface climate. However, models do a poor job of simulating the QBO in the lower stratosphere, for reasons that remain unclear. One possibility is that models do not completely represent how ozone influences the QBO-associated wind variations. Here we propose a multi-model framework for assessing how ozone influences the QBO in recent past and future climates.
Calum P. Wilson and Michael J. Prather
Atmos. Meas. Tech., 18, 1757–1769, https://doi.org/10.5194/amt-18-1757-2025, https://doi.org/10.5194/amt-18-1757-2025, 2025
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We evaluated how well we can infer air pollutant levels (ozone, carbon monoxide, and nitrogen oxides) between air quality stations throughout South Korea, finding good representation in most densely measured cities in spite of intense small-scale emission hotspots. Comparing observed air quality with gridded model output is desirable, and so we created gridded datasets over South Korea using air quality station measurements, which agreed with airborne measurements around Seoul.
Maryam Ramezani Ziarani, Miriam Sinnhuber, Thomas Reddmann, Bernd Funke, Stefan Bender, and Michael Prather
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-227, https://doi.org/10.5194/gmd-2024-227, 2025
Revised manuscript accepted for GMD
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Our study aims to present a new method for incorporating top-down solar forcing into stratospheric ozone relying on linearized ozone scheme. The addition of geomagnetic forcing led to significant ozone losses in the polar upper stratosphere of both hemispheres due to the catalytic cycles involving NOy. In addition to the particle precipitation effect, accounting for solar UV variability in the ICON-ART model leads to the changes in ozone in the tropical stratosphere.
Hanqin Tian, Naiqing Pan, Rona L. Thompson, Josep G. Canadell, Parvadha Suntharalingam, Pierre Regnier, Eric A. Davidson, Michael Prather, Philippe Ciais, Marilena Muntean, Shufen Pan, Wilfried Winiwarter, Sönke Zaehle, Feng Zhou, Robert B. Jackson, Hermann W. Bange, Sarah Berthet, Zihao Bian, Daniele Bianchi, Alexander F. Bouwman, Erik T. Buitenhuis, Geoffrey Dutton, Minpeng Hu, Akihiko Ito, Atul K. Jain, Aurich Jeltsch-Thömmes, Fortunat Joos, Sian Kou-Giesbrecht, Paul B. Krummel, Xin Lan, Angela Landolfi, Ronny Lauerwald, Ya Li, Chaoqun Lu, Taylor Maavara, Manfredi Manizza, Dylan B. Millet, Jens Mühle, Prabir K. Patra, Glen P. Peters, Xiaoyu Qin, Peter Raymond, Laure Resplandy, Judith A. Rosentreter, Hao Shi, Qing Sun, Daniele Tonina, Francesco N. Tubiello, Guido R. van der Werf, Nicolas Vuichard, Junjie Wang, Kelley C. Wells, Luke M. Western, Chris Wilson, Jia Yang, Yuanzhi Yao, Yongfa You, and Qing Zhu
Earth Syst. Sci. Data, 16, 2543–2604, https://doi.org/10.5194/essd-16-2543-2024, https://doi.org/10.5194/essd-16-2543-2024, 2024
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Atmospheric concentrations of nitrous oxide (N2O), a greenhouse gas 273 times more potent than carbon dioxide, have increased by 25 % since the preindustrial period, with the highest observed growth rate in 2020 and 2021. This rapid growth rate has primarily been due to a 40 % increase in anthropogenic emissions since 1980. Observed atmospheric N2O concentrations in recent years have exceeded the worst-case climate scenario, underscoring the importance of reducing anthropogenic N2O emissions.
Hsiang-He Lee, Qi Tang, and Michael Prather
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-203, https://doi.org/10.5194/gmd-2023-203, 2024
Revised manuscript not accepted
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The E3SM Chemistry diagnostics package (ChemDyg) is a software tool, which is designed for the global climate model (E3SM) chemistry development. ChemDyg generates several diagnostic plots and tables for model-to-model and model-to-observation comparison, including 2-dimentional contour mapping plots, diurnal and annual cycle, time-series plots, and comprehensive processing tables. This paper is to introduce the details of each diagnostics set and its required input data formats in ChemDyg.
Michael J. Prather, Hao Guo, and Xin Zhu
Earth Syst. Sci. Data, 15, 3299–3349, https://doi.org/10.5194/essd-15-3299-2023, https://doi.org/10.5194/essd-15-3299-2023, 2023
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The Atmospheric Tomography Mission (ATom) measured the chemical composition in air parcels from 0–12 km altitude on 2 km horizontal by 80 m vertical scales for four seasons, resolving most scales of chemical heterogeneity. ATom is one of the first missions designed to calculate the chemical evolution of each parcel, providing semi-global diurnal budgets for ozone and methane. Observations covered the remote troposphere: Pacific and Atlantic Ocean basins, Southern Ocean, Arctic basin, Antarctica.
Michael J. Prather, Lucien Froidevaux, and Nathaniel J. Livesey
Atmos. Chem. Phys., 23, 843–849, https://doi.org/10.5194/acp-23-843-2023, https://doi.org/10.5194/acp-23-843-2023, 2023
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From satellite data for nitrous oxide (N2O), ozone and temperature, we calculate the monthly loss of N2O and find it is increasing faster than expected, resulting in a shorter lifetime, which reduces the impact of anthropogenic emissions. We identify the cause as enhanced vertical lofting of high-N2O air into the tropical middle stratosphere, where it is destroyed photochemically. Because global warming is due in part to N2O, this finding presents a new negative climate-chemistry feedback.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven C. Wofsy
Atmos. Chem. Phys., 23, 99–117, https://doi.org/10.5194/acp-23-99-2023, https://doi.org/10.5194/acp-23-99-2023, 2023
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We have prepared a unique and unusual result from the recent ATom aircraft mission: a measurement-based derivation of the production and loss rates of ozone and methane over the ocean basins. These are the key products of chemistry models used in assessments but have thus far lacked observational metrics. It also shows the scales of variability of atmospheric chemical rates and provides a major challenge to the atmospheric models.
Daniel J. Ruiz and Michael J. Prather
Atmos. Chem. Phys., 22, 2079–2093, https://doi.org/10.5194/acp-22-2079-2022, https://doi.org/10.5194/acp-22-2079-2022, 2022
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The stratosphere is an important source of tropospheric ozone, which affects climate, chemistry, and air quality, but is extremely difficult to quantify given the large production and loss terms in the troposphere. Here, we use other gases that are well observed and quantified as a reference to test our simulations of ozone transport in the atmosphere. This allows us to better constrain the stratospheric source of ozone and also offers guidance to improve future simulations of ozone transport.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven Wofsy
Atmos. Chem. Phys., 21, 13729–13746, https://doi.org/10.5194/acp-21-13729-2021, https://doi.org/10.5194/acp-21-13729-2021, 2021
Short summary
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The NASA Atmospheric Tomography (ATom) mission built a climatology of the chemical composition of tropospheric air parcels throughout the middle of the Pacific and Atlantic oceans. The level of detail allows us to reconstruct the photochemical budgets of O3 and CH4 over these vast, remote regions. We find that most of the chemical heterogeneity is captured at the resolution used in current global chemistry models and that the majority of reactivity occurs in the
hottest20 % of parcels.
Qi Tang, Michael J. Prather, Juno Hsu, Daniel J. Ruiz, Philip J. Cameron-Smith, Shaocheng Xie, and Jean-Christophe Golaz
Geosci. Model Dev., 14, 1219–1236, https://doi.org/10.5194/gmd-14-1219-2021, https://doi.org/10.5194/gmd-14-1219-2021, 2021
Jinbo Xie, Qi Tang, Michael Prather, Jadwiga Richter, and Shixuan Zhang
Atmos. Chem. Phys., 25, 9315–9333, https://doi.org/10.5194/acp-25-9315-2025, https://doi.org/10.5194/acp-25-9315-2025, 2025
Short summary
Short summary
Analysis of the interaction between the climate and ozone in the stratosphere is complicated by the inability of climate models to simulate the quasi-biennial oscillation (QBO) – an important climate mode in the stratosphere. We use a set of model simulations that realistically simulate QBO and a novel ozone diagnostic tool to separate temperature- and circulation-driven QBO impacts. These are important for diagnosing model–model differences in QBO–ozone responses for climate projections.
Paul T. Griffiths, Laura J. Wilcox, Robert J. Allen, Vaishali Naik, Fiona M. O'Connor, Michael Prather, Alex Archibald, Florence Brown, Makoto Deushi, William Collins, Stephanie Fiedler, Naga Oshima, Lee T. Murray, Bjørn H. Samset, Chris Smith, Steven Turnock, Duncan Watson-Parris, and Paul J. Young
Atmos. Chem. Phys., 25, 8289–8328, https://doi.org/10.5194/acp-25-8289-2025, https://doi.org/10.5194/acp-25-8289-2025, 2025
Short summary
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The Aerosol Chemistry Model Intercomparison Project (AerChemMIP) aimed to quantify the climate and air quality impacts of aerosols and chemically reactive gases. We review its contribution to AR6 (Sixth Assessment Report of the Intergovernmental Panel on Climate Change) and the wider understanding of the role of these species in climate and climate change. We identify challenges and provide recommendations to improve the utility and uptake of climate model data, detailed summary tables of CMIP6 models, experiments, and emergent diagnostics.
Clara Orbe, Alison Ming, Gabriel Chiodo, Michael Prather, Mohamadou Diallo, Qi Tang, Andreas Chrysanthou, Hiroaki Naoe, Xin Zhou, Irina Thaler, Dillon Elsbury, Ewa Bednarz, Jonathon S. Wright, Aaron Match, Shingo Watanabe, James Anstey, Tobias Kerzenmacher, Stefan Versick, Marion Marchand, Feng Li, and James Keeble
EGUsphere, https://doi.org/10.5194/egusphere-2025-2761, https://doi.org/10.5194/egusphere-2025-2761, 2025
Short summary
Short summary
The quasi-biennial oscillation (QBO) is the main source of wind fluctuations in the tropical stratosphere, which can couple to surface climate. However, models do a poor job of simulating the QBO in the lower stratosphere, for reasons that remain unclear. One possibility is that models do not completely represent how ozone influences the QBO-associated wind variations. Here we propose a multi-model framework for assessing how ozone influences the QBO in recent past and future climates.
Calum P. Wilson and Michael J. Prather
Atmos. Meas. Tech., 18, 1757–1769, https://doi.org/10.5194/amt-18-1757-2025, https://doi.org/10.5194/amt-18-1757-2025, 2025
Short summary
Short summary
We evaluated how well we can infer air pollutant levels (ozone, carbon monoxide, and nitrogen oxides) between air quality stations throughout South Korea, finding good representation in most densely measured cities in spite of intense small-scale emission hotspots. Comparing observed air quality with gridded model output is desirable, and so we created gridded datasets over South Korea using air quality station measurements, which agreed with airborne measurements around Seoul.
Maryam Ramezani Ziarani, Miriam Sinnhuber, Thomas Reddmann, Bernd Funke, Stefan Bender, and Michael Prather
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2024-227, https://doi.org/10.5194/gmd-2024-227, 2025
Revised manuscript accepted for GMD
Short summary
Short summary
Our study aims to present a new method for incorporating top-down solar forcing into stratospheric ozone relying on linearized ozone scheme. The addition of geomagnetic forcing led to significant ozone losses in the polar upper stratosphere of both hemispheres due to the catalytic cycles involving NOy. In addition to the particle precipitation effect, accounting for solar UV variability in the ICON-ART model leads to the changes in ozone in the tropical stratosphere.
Hanqin Tian, Naiqing Pan, Rona L. Thompson, Josep G. Canadell, Parvadha Suntharalingam, Pierre Regnier, Eric A. Davidson, Michael Prather, Philippe Ciais, Marilena Muntean, Shufen Pan, Wilfried Winiwarter, Sönke Zaehle, Feng Zhou, Robert B. Jackson, Hermann W. Bange, Sarah Berthet, Zihao Bian, Daniele Bianchi, Alexander F. Bouwman, Erik T. Buitenhuis, Geoffrey Dutton, Minpeng Hu, Akihiko Ito, Atul K. Jain, Aurich Jeltsch-Thömmes, Fortunat Joos, Sian Kou-Giesbrecht, Paul B. Krummel, Xin Lan, Angela Landolfi, Ronny Lauerwald, Ya Li, Chaoqun Lu, Taylor Maavara, Manfredi Manizza, Dylan B. Millet, Jens Mühle, Prabir K. Patra, Glen P. Peters, Xiaoyu Qin, Peter Raymond, Laure Resplandy, Judith A. Rosentreter, Hao Shi, Qing Sun, Daniele Tonina, Francesco N. Tubiello, Guido R. van der Werf, Nicolas Vuichard, Junjie Wang, Kelley C. Wells, Luke M. Western, Chris Wilson, Jia Yang, Yuanzhi Yao, Yongfa You, and Qing Zhu
Earth Syst. Sci. Data, 16, 2543–2604, https://doi.org/10.5194/essd-16-2543-2024, https://doi.org/10.5194/essd-16-2543-2024, 2024
Short summary
Short summary
Atmospheric concentrations of nitrous oxide (N2O), a greenhouse gas 273 times more potent than carbon dioxide, have increased by 25 % since the preindustrial period, with the highest observed growth rate in 2020 and 2021. This rapid growth rate has primarily been due to a 40 % increase in anthropogenic emissions since 1980. Observed atmospheric N2O concentrations in recent years have exceeded the worst-case climate scenario, underscoring the importance of reducing anthropogenic N2O emissions.
Hsiang-He Lee, Qi Tang, and Michael Prather
Geosci. Model Dev. Discuss., https://doi.org/10.5194/gmd-2023-203, https://doi.org/10.5194/gmd-2023-203, 2024
Revised manuscript not accepted
Short summary
Short summary
The E3SM Chemistry diagnostics package (ChemDyg) is a software tool, which is designed for the global climate model (E3SM) chemistry development. ChemDyg generates several diagnostic plots and tables for model-to-model and model-to-observation comparison, including 2-dimentional contour mapping plots, diurnal and annual cycle, time-series plots, and comprehensive processing tables. This paper is to introduce the details of each diagnostics set and its required input data formats in ChemDyg.
Michael J. Prather, Hao Guo, and Xin Zhu
Earth Syst. Sci. Data, 15, 3299–3349, https://doi.org/10.5194/essd-15-3299-2023, https://doi.org/10.5194/essd-15-3299-2023, 2023
Short summary
Short summary
The Atmospheric Tomography Mission (ATom) measured the chemical composition in air parcels from 0–12 km altitude on 2 km horizontal by 80 m vertical scales for four seasons, resolving most scales of chemical heterogeneity. ATom is one of the first missions designed to calculate the chemical evolution of each parcel, providing semi-global diurnal budgets for ozone and methane. Observations covered the remote troposphere: Pacific and Atlantic Ocean basins, Southern Ocean, Arctic basin, Antarctica.
Michael J. Prather, Lucien Froidevaux, and Nathaniel J. Livesey
Atmos. Chem. Phys., 23, 843–849, https://doi.org/10.5194/acp-23-843-2023, https://doi.org/10.5194/acp-23-843-2023, 2023
Short summary
Short summary
From satellite data for nitrous oxide (N2O), ozone and temperature, we calculate the monthly loss of N2O and find it is increasing faster than expected, resulting in a shorter lifetime, which reduces the impact of anthropogenic emissions. We identify the cause as enhanced vertical lofting of high-N2O air into the tropical middle stratosphere, where it is destroyed photochemically. Because global warming is due in part to N2O, this finding presents a new negative climate-chemistry feedback.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven C. Wofsy
Atmos. Chem. Phys., 23, 99–117, https://doi.org/10.5194/acp-23-99-2023, https://doi.org/10.5194/acp-23-99-2023, 2023
Short summary
Short summary
We have prepared a unique and unusual result from the recent ATom aircraft mission: a measurement-based derivation of the production and loss rates of ozone and methane over the ocean basins. These are the key products of chemistry models used in assessments but have thus far lacked observational metrics. It also shows the scales of variability of atmospheric chemical rates and provides a major challenge to the atmospheric models.
Daniel J. Ruiz and Michael J. Prather
Atmos. Chem. Phys., 22, 2079–2093, https://doi.org/10.5194/acp-22-2079-2022, https://doi.org/10.5194/acp-22-2079-2022, 2022
Short summary
Short summary
The stratosphere is an important source of tropospheric ozone, which affects climate, chemistry, and air quality, but is extremely difficult to quantify given the large production and loss terms in the troposphere. Here, we use other gases that are well observed and quantified as a reference to test our simulations of ozone transport in the atmosphere. This allows us to better constrain the stratospheric source of ozone and also offers guidance to improve future simulations of ozone transport.
Hao Guo, Clare M. Flynn, Michael J. Prather, Sarah A. Strode, Stephen D. Steenrod, Louisa Emmons, Forrest Lacey, Jean-Francois Lamarque, Arlene M. Fiore, Gus Correa, Lee T. Murray, Glenn M. Wolfe, Jason M. St. Clair, Michelle Kim, John Crounse, Glenn Diskin, Joshua DiGangi, Bruce C. Daube, Roisin Commane, Kathryn McKain, Jeff Peischl, Thomas B. Ryerson, Chelsea Thompson, Thomas F. Hanisco, Donald Blake, Nicola J. Blake, Eric C. Apel, Rebecca S. Hornbrook, James W. Elkins, Eric J. Hintsa, Fred L. Moore, and Steven Wofsy
Atmos. Chem. Phys., 21, 13729–13746, https://doi.org/10.5194/acp-21-13729-2021, https://doi.org/10.5194/acp-21-13729-2021, 2021
Short summary
Short summary
The NASA Atmospheric Tomography (ATom) mission built a climatology of the chemical composition of tropospheric air parcels throughout the middle of the Pacific and Atlantic oceans. The level of detail allows us to reconstruct the photochemical budgets of O3 and CH4 over these vast, remote regions. We find that most of the chemical heterogeneity is captured at the resolution used in current global chemistry models and that the majority of reactivity occurs in the
hottest20 % of parcels.
Qi Tang, Michael J. Prather, Juno Hsu, Daniel J. Ruiz, Philip J. Cameron-Smith, Shaocheng Xie, and Jean-Christophe Golaz
Geosci. Model Dev., 14, 1219–1236, https://doi.org/10.5194/gmd-14-1219-2021, https://doi.org/10.5194/gmd-14-1219-2021, 2021
Cited articles
Baker, D. F., Law, R. M., Gurney, K. R., Rayner, P., Peylin, P., Denning, A. S., Bousquet, P., Bruhwiler, L., Chen, Y. H., Ciais, P., Fung, I. Y., Heimann, M., John, J., Maki, T., Maksyutov, S., Masarie, K., Prather, M., Pak, B., Taguchi, S., and Zhu, Z.: TransCom 3 inversion intercomparison: Impact of transport model errors on the interannual variability of regional CO2 fluxes, 1988–2003, Global Biogeochem. Cy., 20, Gb1002, https://doi.org/10.1029/2004gb002439, 2006.
Cunnold, D. M., Fraser, P. J., Weiss, R. F., Prinn, R. G., Simmonds, P. G., Miller, B. R., Alyea, F. N., and Crawford, A. J.: Global trends and annual releases of CCl3F and CCl2F2 estimated from ALE/GAGE and other measurements from July 1978 to June 1991, J. Geophys. Res., 99, 1107–1126, https://doi.org/10.1029/93JD02715, 1994.
Deng, F., Jones, D. B. A., Walker, T. W., Keller, M., Bowman, K. W., Henze, D. K., Nassar, R., Kort, E. A., Wofsy, S. C., Walker, K. A., Bourassa, A. E., and Degenstein, D. A.: Sensitivity analysis of the potential impact of discrepancies in stratosphere–troposphere exchange on inferred sources and sinks of CO2, Atmos. Chem. Phys., 15, 11773–11788, https://doi.org/10.5194/acp-15-11773-2015, 2015.
Dlugokencky, E. J., Crotwell, A. M., Mund, J. W., Crotwell, M. J., and Thoning, K. W.: Atmospheric Nitrous Oxide Dry Air Mole Fractions from the NOAA GML Carbon Cycle Cooperative Global Air Sampling Network, 1997–2020, Version: 2021-07-30, NOAA Global Monitoring Laboratory Data Repository [data set], https://doi.org/10.15138/53g1-x417, 2021a.
Dlugokencky, E. J., Mund, J. W., Crotwell, A. M., Crotwell, M. J., and Thoning, K. W.: Atmospheric Carbon Dioxide Dry Air Mole Fractions from the NOAA GML Carbon Cycle Cooperative Global Air Sampling Network, 1968–2020, Version: 2021-07-30, NOAA Global Monitoring Laboratory Data Repository [data set], https://doi.org/10.15138/wkgj-f215, 2021b.
Engelen, R. J., Denning, A. S., Gurney, K. R., Law, R. M., Denning, A. S., Rayner, P. J., Baker, D., Bousquet, P., Bruhwiler, L., Chen, Y. H., Ciais, P., Fan, S., Fung, I. Y., Gloor, M., Heimann, M., Higuchi, K., John, J., Maki, T., Maksyutov, S., Masarie, K., Peylin, P., Prather, M., Pak, B. C., Sarmiento, J., Taguchi, S., Takahashi, T., and Yuen, C. W.: On error estimation in atmospheric CO2 inversions, J. Geophys. Res.-Atmos., 111, D14199, https://doi.org/10.1029/2006jd007428, 2006.
Frankenberg, C., Kulawik, S. S., Wofsy, S. C., Chevallier, F., Daube, B., Kort, E. A., O'Dell, C., Olsen, E. T., and Osterman, G.: Using airborne HIAPER Pole-to-Pole Observations (HIPPO) to evaluate model and remote sensing estimates of atmospheric carbon dioxide, Atmos. Chem. Phys., 16, 7867–7878, https://doi.org/10.5194/acp-16-7867-2016, 2016.
Gaubert, B., Stephens, B. B., Basu, S., Chevallier, F., Deng, F., Kort, E. A., Patra, P. K., Peters, W., Rödenbeck, C., Saeki, T., Schimel, D., Van der Laan-Luijkx, I., Wofsy, S., and Yin, Y.: Global atmospheric CO2 inverse models converging on neutral tropical land exchange, but disagreeing on fossil fuel and atmospheric growth rate, Biogeosciences, 16, 117–134, https://doi.org/10.5194/bg-16-117-2019, 2019.
Graven, H. D., Keeling, R. F., Piper, S. C., Patra, P. K., Stephens, B. B., Wofsy, S. C., Welp, L. R., Sweeney, C., Tans, P. P., Kelley, J. J., Daube, B. C., Kort, E. A., Santoni, G. W., and Bent, J. D.: Enhanced Seasonal Exchange of CO2 by Northern Ecosystems Since 1960, Science, 341, 1085–1089, https://doi.org/10.1126/science.1239207, 2013.
Gurney, K. R., Law, R. M., Denning, A. S., Rayner, P. J., Baker, D., Bousquet, P., Bruhwiler, L., Chen, Y. H., Ciais, P., Fan, S., Fung, I. Y., Gloor, M., Heimann, M., Higuchi, K., John, J., Maki, T., Maksyutov, S., Masarie, K., Peylin, P., Prather, M., Pak, B. C., Randerson, J., Sarmiento, J., Taguchi, S., Takahashi, T., and Yuen, C. W.: Towards robust regional estimates of CO2 sources and sinks using atmospheric transport models, Nature, 415, 626–630, https://doi.org/10.1038/415626a, 2002.
Hamilton, K. and Fan, S. M.: Effects of the stratospheric quasi-biennial oscillation on long-lived greenhouse gases in the troposphere, J. Geophys. Res.-Atmos., 105, 20581–20587, https://doi.org/10.1029/2000jd900331, 2000.
Keeling, R. F. and Graven, H. D.: Insights from Time Series of Atmospheric Carbon Dioxide and Related Tracers, Annu. Rev. Env. Resour., 46, 85–110, https://doi.org/10.1146/annurev-environ-012220-125406, 2021.
Koren, G., Schneider, L., van der Velde, I. R., van Schaik, E., Gromov, S. S., Adnew, G. A., Martino, D. J. M., Hofmann, M. E. G., Liang, M. C., Mahata, S., Bergamaschi, P., van der Laan-Luijkx, I. T., Krol, M. C., Rockmann, T., and Peters, W.: Global 3-D Simulations of the triple oxygen isotope signature delta O-17 in atmospheric CO2, J. Geophys. Res.-Atmos., 124, 8808–8836, https://doi.org/10.1029/2019JD030387, 2019.
Laskar, A. H., Mahata, S., Bhattacharya, S. K., and Liang, M. C.: Triple oxygen and clumped isotope compositions of CO2 in the middle troposphere, Earth Space Sci., 6, 1205–1219, https://doi.org/10.1029/2019EA000573, 2019.
Le Quéré, C., Andrew, R. M., Canadell, J. G., Sitch, S., Korsbakken, J. I., Peters, G. P., Manning, A. C., Boden, T. A., Tans, P. P., Houghton, R. A., Keeling, R. F., Alin, S., Andrews, O. D., Anthoni, P., Barbero, L., Bopp, L., Chevallier, F., Chini, L. P., Ciais, P., Currie, K., Delire, C., Doney, S. C., Friedlingstein, P., Gkritzalis, T., Harris, I., Hauck, J., Haverd, V., Hoppema, M., Klein Goldewijk, K., Jain, A. K., Kato, E., Körtzinger, A., Landschützer, P., Lefèvre, N., Lenton, A., Lienert, S., Lombardozzi, D., Melton, J. R., Metzl, N., Millero, F., Monteiro, P. M. S., Munro, D. R., Nabel, J. E. M. S., Nakaoka, S., O'Brien, K., Olsen, A., Omar, A. M., Ono, T., Pierrot, D., Poulter, B., Rödenbeck, C., Salisbury, J., Schuster, U., Schwinger, J., Séférian, R., Skjelvan, I., Stocker, B. D., Sutton, A. J., Takahashi, T., Tian, H., Tilbrook, B., van der Laan-Luijkx, I. T., van der Werf, G. R., Viovy, N., Walker, A. P., Wiltshire, A. J., and Zaehle, S.: Global Carbon Budget 2016, Earth Syst. Sci. Data, 8, 605–649, https://doi.org/10.5194/essd-8-605-2016, 2016.
Liang, M. C., Mahata, S., Laskar, A. H., Thiemens, M. H., and Newman, S.: Oxygen isotope anomaly in tropospheric CO2 and implications for CO2 residence time in the atmosphere and gross primary productivity, Sci. Rep.-UK, 7, 13180, https://doi.org/10.1038/S41598-017-12774-W, 2017.
McNorton, J. R., Bousserez, N., Agustí-Panareda, A., Balsamo, G., Choulga, M., Dawson, A., Engelen, R., Kipling, Z., and Lang, S.: Representing model uncertainty for global atmospheric CO2 flux inversions using ECMWF-IFS-46R1, Geosci. Model Dev., 13, 2297–2313, https://doi.org/10.5194/gmd-13-2297-2020, 2020.
Nakazawa, T.: Current understanding of the global cycling of carbon dioxide, methane, and nitrous oxide, P. Jpn. Acad. B-Phys., 96, 394–419, https://doi.org/10.2183/pjab.96.030, 2020.
Nassar, R., Jones, D. B. A., Kulawik, S. S., Worden, J. R., Bowman, K. W., Andres, R. J., Suntharalingam, P., Chen, J. M., Brenninkmeijer, C. A. M., Schuck, T. J., Conway, T. J., and Worthy, D. E.: Inverse modeling of CO2 sources and sinks using satellite observations of CO2 from TES and surface flask measurements, Atmos. Chem. Phys., 11, 6029–6047, https://doi.org/10.5194/acp-11-6029-2011, 2011.
Nevison, C. D., Kinnison, D. E., and Weiss, R. F.: Stratospheric influences on the tropospheric seasonal cycles of nitrous oxide and chlorofluorocarbons, Geophys. Res. Lett., 31, L20103, https://doi.org/10.1029/2004gl020398, 2004.
Nevison, C. D., Mahowald, N. M., Weiss, R. F., and Prinn, R. G.: Interannual and seasonal variability in atmospheric N2O, Global Biogeochem. Cy., 21, GB3017, https://doi.org/10.1029/2006GB002755, 2007.
Nevison, C. D., Dlugokencky, E., Dutton, G., Elkins, J. W., Fraser, P., Hall, B., Krummel, P. B., Langenfelds, R. L., O'Doherty, S., Prinn, R. G., Steele, L. P., and Weiss, R. F.: Exploring causes of interannual variability in the seasonal cycles of tropospheric nitrous oxide, Atmos. Chem. Phys., 11, 3713–3730, https://doi.org/10.5194/acp-11-3713-2011, 2011.
Newman, P.: The quasi-biennial oscillation (QBO), NASA, Goddard Space Flight Center, https://acd-ext.gsfc.nasa.gov/Data_services/met/qbo/qbo.html, last access: 30 August 2021.
Pandey, S., Houweling, S., Krol, M., Aben, I., Chevallier, F., Dlugokencky, E. J., Gatti, L. V., Gloor, E., Miller, J. B., Detmers, R., Machida, T., and Röckmann, T.: Inverse modeling of GOSAT-retrieved ratios of total column CH4 and CO2 for 2009 and 2010, Atmos. Chem. Phys., 16, 5043–5062, https://doi.org/10.5194/acp-16-5043-2016, 2016.
Peylin, P., Law, R. M., Gurney, K. R., Chevallier, F., Jacobson, A. R., Maki, T., Niwa, Y., Patra, P. K., Peters, W., Rayner, P. J., Rödenbeck, C., van der Laan-Luijkx, I. T., and Zhang, X.: Global atmospheric carbon budget: results from an ensemble of atmospheric CO2 inversions, Biogeosciences, 10, 6699–6720, https://doi.org/10.5194/bg-10-6699-2013, 2013.
Piao, S. L., Liu, Z., Wang, Y. L., Ciais, P., Yao, Y. T., Peng, S., Chevallier, F., Friedlingstein, P., Janssens, I. A., Penuelas, J., Sitch, S., and Wang, T.: On the causes of trends in the seasonal amplitude of atmospheric CO2, Glob. Change Biol., 24, 608–616, https://doi.org/10.1111/gcb.13909, 2018.
Prather, M.: Surface CO2 variability from the stratosphere, or not, Dryad [data set], https://doi.org/10.7280/D1N10J, 2022.
Ray, E. A., Portmann, R. W., Yu, P. F., Daniel, J., Montzka, S. A., Dutton, G. S., Hall, B. D., Moore, F. L., and Rosenlof, K. H.: The influence of the stratospheric Quasi-Biennial Oscillation on trace gas levels at the Earth's surface, Nat. Geosci., 13, 22, https://doi.org/10.1038/s41561-019-0507-3, 2020.
Ruiz, D. J. and Prather, M. J.: From the middle stratosphere to the surface, using nitrous oxide to constrain the stratosphere–troposphere exchange of ozone, Atmos. Chem. Phys., 22, 2079–2093, https://doi.org/10.5194/acp-22-2079-2022, 2022.
Ruiz, D. J., Prather, M. J., Strahan, S. E., Thompson, R. L., Froidevaux, L., and Steenrod, S. D.: How atmospheric chemistry and transport drive surface variability of N2O and CFC-11, J. Geophys. Res.-Atmos., 126, e2020JD033979, https://doi.org/10.1029/2020JD033979, 2021.
Tang, Q., Prather, M. J., Hsu, J., Ruiz, D. J., Cameron-Smith, P. J., Xie, S., and Golaz, J.-C.: Evaluation of the interactive stratospheric ozone (O3v2) module in the E3SM version 1 Earth system model, Geosci. Model Dev., 14, 1219–1236, https://doi.org/10.5194/gmd-14-1219-2021, 2021.
Trenberth, K. and National Center for Atmospheric
Research Staff (Eds.): The Climate Data Guide: Nino SST Indices
(Nino 1+2, 3, 3.4, 4; ONI and TNI), last modified: 21 January 2020,
https://climatedataguide.ucar.edu/climate-data/nino-sst-indices-nino-12-3-34-4-oni-and-tni
(last access: 1 June 2021), 2020.
Tung, K. K. and Yang, H.: Global QBO in circulation and ozone 2. A simple mechanistic model, J. Atmos. Sci., 51, 2708–2721, https://doi.org/10.1175/1520-0469(1994)051<2708:Gqicao>2.0.Co;2, 1994.
Wang, K., Wang, Y. L., Wang, X. H., He, Y., Li, X. Y., Keeling, R. F., Ciais, P., Heimann, M., Peng, S. S., Chevallier, F., Friedlingstein, P., Sitch, S., Buermann, W., Arora, V. K., Haverd, V., Jain, A. K., Kato, E., Lienert, S., Lombardozzi, D., Nabel, J. E. M. S., Poulter, B., Vuichard, N., Wiltshire, A., Zeng, N., Zhu, D., and Piao, S. L.: Causes of slowing-down seasonal CO2 amplitude at Mauna Loa, Glob. Change Biol., 26, 4462–4477, https://doi.org/10.1111/gcb.15162, 2020.
Wang, K., Wang, X. H., Piao, S. L., Chevallier, F., Mao, J. F., Shi, X. Y., Huntingford, C., Bastos, A., Ciais, P., Xu, H., Keeling, R. F., Pacala, S. W., and Chen, A. P.: Unusual characteristics of the carbon cycle during the 2015–2016 El Nino, Glob. Change Biol., 27, 3798–3809, https://doi.org/10.1111/gcb.15669, 2021.
Wenzel, S., Cox, P. M., Eyring, V., and Friedlingstein, P.: Projected land photosynthesis constrained by changes in the seasonal cycle of atmospheric CO2, Nature, 538, 499–501, https://doi.org/10.1038/nature19772, 2016.
Zhao, F. and Zeng, N.: Continued increase in atmospheric CO2 seasonal amplitude in the 21st century projected by the CMIP5 Earth system models, Earth Syst. Dynam., 5, 423–439, https://doi.org/10.5194/esd-5-423-2014, 2014.
Short summary
Atmospheric CO2 fluctuations point to changes in fossil fuel emissions plus natural and perturbed variations in the natural carbon cycle. One unstudied source of variability is the stratosphere, where the influx of aged CO2-depleted air can cause surface fluctuations. Using modeling and, separately, scaling the observed N2O variability, I find that stratosphere-driven surface variability in CO2 is not a significant uncertainty (at most 10 % of the observed interannual variability).
Atmospheric CO2 fluctuations point to changes in fossil fuel emissions plus natural and...
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